Methyl 2-amino-4-(3-chloro­prop­oxy)-5-methoxy­benzoate

The asymmetric unit of the title compound, C(12)H(16)ClNO(4), contains two crystallographically independent mol­ecules. The benzene rings of the two independent mol­ecules are oriented at a dihedral angle of 88.50 (3)°. Intra­molecular N—H⋯O hydrogen bonds involving the methoxybenzoate carbonyl grou...

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Detalles Bibliográficos
Autores principales: Zhang, Min, Lu, Ran-zhe, Han, Lu-na, Wei, Wen-bin, Wang, Hai-bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977643/
https://www.ncbi.nlm.nih.gov/pubmed/21583986
http://dx.doi.org/10.1107/S1600536809011374
Descripción
Sumario:The asymmetric unit of the title compound, C(12)H(16)ClNO(4), contains two crystallographically independent mol­ecules. The benzene rings of the two independent mol­ecules are oriented at a dihedral angle of 88.50 (3)°. Intra­molecular N—H⋯O hydrogen bonds involving the methoxybenzoate carbonyl group in each molecule result in the formation of two planar, six-membered rings, oriented at dihedral angles of 1.39 (3) and 0.68 (3)° with respect to the adjacent benzene rings. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains along the a axis.

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