Methyl 2-amino-4-(3-chloro­prop­oxy)-5-methoxy­benzoate

The asymmetric unit of the title compound, C(12)H(16)ClNO(4), contains two crystallographically independent mol­ecules. The benzene rings of the two independent mol­ecules are oriented at a dihedral angle of 88.50 (3)°. Intra­molecular N—H⋯O hydrogen bonds involving the methoxybenzoate carbonyl grou...

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Detalles Bibliográficos
Autores principales: Zhang, Min, Lu, Ran-zhe, Han, Lu-na, Wei, Wen-bin, Wang, Hai-bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977643/
https://www.ncbi.nlm.nih.gov/pubmed/21583986
http://dx.doi.org/10.1107/S1600536809011374
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author Zhang, Min
Lu, Ran-zhe
Han, Lu-na
Wei, Wen-bin
Wang, Hai-bo
author_facet Zhang, Min
Lu, Ran-zhe
Han, Lu-na
Wei, Wen-bin
Wang, Hai-bo
author_sort Zhang, Min
collection PubMed
description The asymmetric unit of the title compound, C(12)H(16)ClNO(4), contains two crystallographically independent mol­ecules. The benzene rings of the two independent mol­ecules are oriented at a dihedral angle of 88.50 (3)°. Intra­molecular N—H⋯O hydrogen bonds involving the methoxybenzoate carbonyl group in each molecule result in the formation of two planar, six-membered rings, oriented at dihedral angles of 1.39 (3) and 0.68 (3)° with respect to the adjacent benzene rings. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains along the a axis.
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spelling pubmed-29776432010-12-30 Methyl 2-amino-4-(3-chloro­prop­oxy)-5-methoxy­benzoate Zhang, Min Lu, Ran-zhe Han, Lu-na Wei, Wen-bin Wang, Hai-bo Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(12)H(16)ClNO(4), contains two crystallographically independent mol­ecules. The benzene rings of the two independent mol­ecules are oriented at a dihedral angle of 88.50 (3)°. Intra­molecular N—H⋯O hydrogen bonds involving the methoxybenzoate carbonyl group in each molecule result in the formation of two planar, six-membered rings, oriented at dihedral angles of 1.39 (3) and 0.68 (3)° with respect to the adjacent benzene rings. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds link the mol­ecules into chains along the a axis. International Union of Crystallography 2009-04-02 /pmc/articles/PMC2977643/ /pubmed/21583986 http://dx.doi.org/10.1107/S1600536809011374 Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Min
Lu, Ran-zhe
Han, Lu-na
Wei, Wen-bin
Wang, Hai-bo
Methyl 2-amino-4-(3-chloro­prop­oxy)-5-methoxy­benzoate
title Methyl 2-amino-4-(3-chloro­prop­oxy)-5-methoxy­benzoate
title_full Methyl 2-amino-4-(3-chloro­prop­oxy)-5-methoxy­benzoate
title_fullStr Methyl 2-amino-4-(3-chloro­prop­oxy)-5-methoxy­benzoate
title_full_unstemmed Methyl 2-amino-4-(3-chloro­prop­oxy)-5-methoxy­benzoate
title_short Methyl 2-amino-4-(3-chloro­prop­oxy)-5-methoxy­benzoate
title_sort methyl 2-amino-4-(3-chloro­prop­oxy)-5-methoxy­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977643/
https://www.ncbi.nlm.nih.gov/pubmed/21583986
http://dx.doi.org/10.1107/S1600536809011374
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AT weiwenbin methyl2amino43chloropropoxy5methoxybenzoate
AT wanghaibo methyl2amino43chloropropoxy5methoxybenzoate

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