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2-[(E)-2-(1H-Indol-3-yl)ethenyl]-1-methylpyridinium 4-bromobenzenesulfonate
In the title compound, C(16)H(15)N(2) (+)·C(6)H(4)BrO(3)S(−), the cation exists in the E configuration and is essentially planar with a dihedral angle of 3.10 (5)° between the pyridinium ring and the indole ring system. The π-conjugated planes of the cation and the anion are inclined to each other a...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977651/ https://www.ncbi.nlm.nih.gov/pubmed/21583994 http://dx.doi.org/10.1107/S1600536809011386 |
Sumario: | In the title compound, C(16)H(15)N(2) (+)·C(6)H(4)BrO(3)S(−), the cation exists in the E configuration and is essentially planar with a dihedral angle of 3.10 (5)° between the pyridinium ring and the indole ring system. The π-conjugated planes of the cation and the anion are inclined to each other at a dihedral angle of 64.32 (4)°. In the crystal structure, the cations are stacked in an antiparallel manner along the a axis. The anions are linked into a chain along the a axis. The cations and the anions are linked into a three-dimensional network by N—H⋯O and weak C—H⋯O hydrogen bonds. The crystal structure is further stabilized by C—H⋯π interactions. A π–π interaction between the five-membered heterocyclic ring of the indole system and the pyridinium ring is also observed with a centroid–centroid distance of 3.5855 (7) Å. |
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