3,3′,5,5′-Tetra­bromo-2,2′-bithio­phene

The title compound, C(8)H(2)Br(4)S(2), was prepared by bromination of 2,2′-bithio­phene with bromine. The mol­ecule is located on a crystallographic twofold rotation axis, thereby imposing equal geometry of the two thio­phene rings. Each five-membered ring is planar [maximum deviation 0.011 (9) Å] a...

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Detalles Bibliográficos
Autores principales: Li, Hongqi, Li, Lin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977652/
https://www.ncbi.nlm.nih.gov/pubmed/21583995
http://dx.doi.org/10.1107/S1600536809011647
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author Li, Hongqi
Li, Lin
author_facet Li, Hongqi
Li, Lin
author_sort Li, Hongqi
collection PubMed
description The title compound, C(8)H(2)Br(4)S(2), was prepared by bromination of 2,2′-bithio­phene with bromine. The mol­ecule is located on a crystallographic twofold rotation axis, thereby imposing equal geometry of the two thio­phene rings. Each five-membered ring is planar [maximum deviation 0.011 (9) Å] and the dihedral angle between the planes through the rings is 47.2 (4)°. The mol­ecules are arranged to minimize intramolecular contacts between the 3-3′ and 5-5′-bromine atoms.
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spelling pubmed-29776522010-12-30 3,3′,5,5′-Tetra­bromo-2,2′-bithio­phene Li, Hongqi Li, Lin Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(8)H(2)Br(4)S(2), was prepared by bromination of 2,2′-bithio­phene with bromine. The mol­ecule is located on a crystallographic twofold rotation axis, thereby imposing equal geometry of the two thio­phene rings. Each five-membered ring is planar [maximum deviation 0.011 (9) Å] and the dihedral angle between the planes through the rings is 47.2 (4)°. The mol­ecules are arranged to minimize intramolecular contacts between the 3-3′ and 5-5′-bromine atoms. International Union of Crystallography 2009-04-02 /pmc/articles/PMC2977652/ /pubmed/21583995 http://dx.doi.org/10.1107/S1600536809011647 Text en © Li and Li 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Hongqi
Li, Lin
3,3′,5,5′-Tetra­bromo-2,2′-bithio­phene
title 3,3′,5,5′-Tetra­bromo-2,2′-bithio­phene
title_full 3,3′,5,5′-Tetra­bromo-2,2′-bithio­phene
title_fullStr 3,3′,5,5′-Tetra­bromo-2,2′-bithio­phene
title_full_unstemmed 3,3′,5,5′-Tetra­bromo-2,2′-bithio­phene
title_short 3,3′,5,5′-Tetra­bromo-2,2′-bithio­phene
title_sort 3,3′,5,5′-tetra­bromo-2,2′-bithio­phene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977652/
https://www.ncbi.nlm.nih.gov/pubmed/21583995
http://dx.doi.org/10.1107/S1600536809011647
work_keys_str_mv AT lihongqi 3355tetrabromo22bithiophene
AT lilin 3355tetrabromo22bithiophene

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