Methyl 5-bromo-2-[meth­yl(methyl­sulfon­yl)amino]benzoate

The title compound, C(10)H(12)BrNO(4)S, is an inter­mediate in the synthesis of benzothia­zine. The planar methyl ester group (maximum deviation is 0.0065 Å) is oriented at a dihedral angle of 39.09 (13)° with respect to the aromatic ring. In the crystal structure, weak inter­molecular C—H⋯O inter­a...

Descripción completa

Detalles Bibliográficos
Autores principales: Shafiq, Muhammad, Tahir, M. Nawaz, Khan, Islam Ullah, Arshad, Muhammad Nadeem, Khan, Muneeb Hayat
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977655/
https://www.ncbi.nlm.nih.gov/pubmed/21583998
http://dx.doi.org/10.1107/S1600536809011829
_version_ 1782191156521598976
author Shafiq, Muhammad
Tahir, M. Nawaz
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Khan, Muneeb Hayat
author_facet Shafiq, Muhammad
Tahir, M. Nawaz
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Khan, Muneeb Hayat
author_sort Shafiq, Muhammad
collection PubMed
description The title compound, C(10)H(12)BrNO(4)S, is an inter­mediate in the synthesis of benzothia­zine. The planar methyl ester group (maximum deviation is 0.0065 Å) is oriented at a dihedral angle of 39.09 (13)° with respect to the aromatic ring. In the crystal structure, weak inter­molecular C—H⋯O inter­actions link the mol­ecules into centrosymmetric dimers, through R (2) (2)(10) ring motifs.
format Text
id pubmed-2977655
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29776552010-12-30 Methyl 5-bromo-2-[meth­yl(methyl­sulfon­yl)amino]benzoate Shafiq, Muhammad Tahir, M. Nawaz Khan, Islam Ullah Arshad, Muhammad Nadeem Khan, Muneeb Hayat Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(12)BrNO(4)S, is an inter­mediate in the synthesis of benzothia­zine. The planar methyl ester group (maximum deviation is 0.0065 Å) is oriented at a dihedral angle of 39.09 (13)° with respect to the aromatic ring. In the crystal structure, weak inter­molecular C—H⋯O inter­actions link the mol­ecules into centrosymmetric dimers, through R (2) (2)(10) ring motifs. International Union of Crystallography 2009-04-02 /pmc/articles/PMC2977655/ /pubmed/21583998 http://dx.doi.org/10.1107/S1600536809011829 Text en © Shafiq et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shafiq, Muhammad
Tahir, M. Nawaz
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Khan, Muneeb Hayat
Methyl 5-bromo-2-[meth­yl(methyl­sulfon­yl)amino]benzoate
title Methyl 5-bromo-2-[meth­yl(methyl­sulfon­yl)amino]benzoate
title_full Methyl 5-bromo-2-[meth­yl(methyl­sulfon­yl)amino]benzoate
title_fullStr Methyl 5-bromo-2-[meth­yl(methyl­sulfon­yl)amino]benzoate
title_full_unstemmed Methyl 5-bromo-2-[meth­yl(methyl­sulfon­yl)amino]benzoate
title_short Methyl 5-bromo-2-[meth­yl(methyl­sulfon­yl)amino]benzoate
title_sort methyl 5-bromo-2-[meth­yl(methyl­sulfon­yl)amino]benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977655/
https://www.ncbi.nlm.nih.gov/pubmed/21583998
http://dx.doi.org/10.1107/S1600536809011829
work_keys_str_mv AT shafiqmuhammad methyl5bromo2methylmethylsulfonylaminobenzoate
AT tahirmnawaz methyl5bromo2methylmethylsulfonylaminobenzoate
AT khanislamullah methyl5bromo2methylmethylsulfonylaminobenzoate
AT arshadmuhammadnadeem methyl5bromo2methylmethylsulfonylaminobenzoate
AT khanmuneebhayat methyl5bromo2methylmethylsulfonylaminobenzoate

Ejemplares similares