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5-(2-Methyl­phen­yl)-1,3,4-thia­diazol-2-amine

The asymmetric unit of the title compound, C(9)H(9)N(3)S, contains two crystallographically independent mol­ecules, in which the thia­diazole and tolyl rings are oriented at dihedral angles of 32.25 (3) and 74.50 (3)°. An intra­molecular C—H⋯S inter­action results in the formation of a five-membered...

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Detalles Bibliográficos
Autores principales: Wang, Yao, Kong, Xiang-Jun, Wan, Rong, Han, Feng, Wang, Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977661/
https://www.ncbi.nlm.nih.gov/pubmed/21584004
http://dx.doi.org/10.1107/S1600536809011234
Descripción
Sumario:The asymmetric unit of the title compound, C(9)H(9)N(3)S, contains two crystallographically independent mol­ecules, in which the thia­diazole and tolyl rings are oriented at dihedral angles of 32.25 (3) and 74.50 (3)°. An intra­molecular C—H⋯S inter­action results in the formation of a five-membered ring. In the crystal structure, inter­molecular N—H⋯N hydrogen bonds link the mol­ecules into chains along the a axis. A π–π contact between the thia­diazole rings [centroid–centroid distance = 3.910 (3) Å] may further stabilize the structure. There is also a weak C—H⋯π inter­action.