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N-[1-(Biphenyl-4-yl)ethylidene]-N′-(2,4-dinitrophenyl)hydrazine
The title compound, C(20)H(16)N(4)O(4), contains two crystallographically independent molecules (A and B) in the asymmetric unit. Intramolecular N—H⋯O hydrogen bonds generate S(6) ring motifs in both molecules. The dihedral angles between the nitro-substituted benzene rings and the two benzene rin...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977666/ https://www.ncbi.nlm.nih.gov/pubmed/21584009 http://dx.doi.org/10.1107/S1600536809009593 |
Sumario: | The title compound, C(20)H(16)N(4)O(4), contains two crystallographically independent molecules (A and B) in the asymmetric unit. Intramolecular N—H⋯O hydrogen bonds generate S(6) ring motifs in both molecules. The dihedral angles between the nitro-substituted benzene rings and the two benzene rings in molecules A and B are 14.32 (9), 17.89 (9)° and 13.04 (9) and 25.71 (9)°. The ortho and para nitro groups form dihedral angles of 6.2 (2) and 8.5 (2)° in molecule A, and 5.3 (3) and 13.8 (2)° in molecule B, with the benzene rings to which they are attached. The crystal structure is stabilized by intermolecular C—H⋯O interactions. |
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