Dimethyl 6,6′-dicyano-2,2′-bipyridine-3,3′-dicarboxyl­ate

In the title compound, C(16)H(10)N(4)O(4), the two pyridine rings are twisted by 44.41 (2)° and the ester groups form dihedral angles of 48.77 (4) and 45.75 (2)° with the corresponding pyridine rings. The crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds and π–π stacking inter­...

Descripción completa

Detalles Bibliográficos
Autores principales: He, Xiao, Qu, Gui-Rong, Deng, Dongsheng, Ji, Baoming
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977680/
https://www.ncbi.nlm.nih.gov/pubmed/21584023
http://dx.doi.org/10.1107/S1600536809012446
_version_ 1782191162590756864
author He, Xiao
Qu, Gui-Rong
Deng, Dongsheng
Ji, Baoming
author_facet He, Xiao
Qu, Gui-Rong
Deng, Dongsheng
Ji, Baoming
author_sort He, Xiao
collection PubMed
description In the title compound, C(16)H(10)N(4)O(4), the two pyridine rings are twisted by 44.41 (2)° and the ester groups form dihedral angles of 48.77 (4) and 45.75 (2)° with the corresponding pyridine rings. The crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridine rings [centroid-to-centroid distance 3.797 (2) Å].
format Text
id pubmed-2977680
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29776802010-12-30 Dimethyl 6,6′-dicyano-2,2′-bipyridine-3,3′-dicarboxyl­ate He, Xiao Qu, Gui-Rong Deng, Dongsheng Ji, Baoming Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(10)N(4)O(4), the two pyridine rings are twisted by 44.41 (2)° and the ester groups form dihedral angles of 48.77 (4) and 45.75 (2)° with the corresponding pyridine rings. The crystal structure is stabilized by inter­molecular C—H⋯O hydrogen bonds and π–π stacking inter­actions between the pyridine rings [centroid-to-centroid distance 3.797 (2) Å]. International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977680/ /pubmed/21584023 http://dx.doi.org/10.1107/S1600536809012446 Text en © He et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
He, Xiao
Qu, Gui-Rong
Deng, Dongsheng
Ji, Baoming
Dimethyl 6,6′-dicyano-2,2′-bipyridine-3,3′-dicarboxyl­ate
title Dimethyl 6,6′-dicyano-2,2′-bipyridine-3,3′-dicarboxyl­ate
title_full Dimethyl 6,6′-dicyano-2,2′-bipyridine-3,3′-dicarboxyl­ate
title_fullStr Dimethyl 6,6′-dicyano-2,2′-bipyridine-3,3′-dicarboxyl­ate
title_full_unstemmed Dimethyl 6,6′-dicyano-2,2′-bipyridine-3,3′-dicarboxyl­ate
title_short Dimethyl 6,6′-dicyano-2,2′-bipyridine-3,3′-dicarboxyl­ate
title_sort dimethyl 6,6′-dicyano-2,2′-bipyridine-3,3′-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977680/
https://www.ncbi.nlm.nih.gov/pubmed/21584023
http://dx.doi.org/10.1107/S1600536809012446
work_keys_str_mv AT hexiao dimethyl66dicyano22bipyridine33dicarboxylate
AT quguirong dimethyl66dicyano22bipyridine33dicarboxylate
AT dengdongsheng dimethyl66dicyano22bipyridine33dicarboxylate
AT jibaoming dimethyl66dicyano22bipyridine33dicarboxylate

Ejemplares similares