4-(2,4-Dichloro­phen­yl)-6-(1H-indol-3-yl)-2,2′-bipyridine-5-carbonitrile

The title compound, C(25)H(14)Cl(2)N(4), crystallizes with two independent mol­ecules in the asymmetric unit. The two pyridine rings are almost coplanar, making dihedral angles of 3.2 (1) and 8.6 (1)° in the two independent mol­ecules. The dichloro­phenyl and indole rings are twisted away from the b...

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Detalles Bibliográficos
Autores principales: Ramesh, P., Sundaresan, S. S., Thirumurugan, P., Perumal, Paramasivan T., Ponnuswamy, M. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977688/
https://www.ncbi.nlm.nih.gov/pubmed/21584031
http://dx.doi.org/10.1107/S1600536809012392
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author Ramesh, P.
Sundaresan, S. S.
Thirumurugan, P.
Perumal, Paramasivan T.
Ponnuswamy, M. N.
author_facet Ramesh, P.
Sundaresan, S. S.
Thirumurugan, P.
Perumal, Paramasivan T.
Ponnuswamy, M. N.
author_sort Ramesh, P.
collection PubMed
description The title compound, C(25)H(14)Cl(2)N(4), crystallizes with two independent mol­ecules in the asymmetric unit. The two pyridine rings are almost coplanar, making dihedral angles of 3.2 (1) and 8.6 (1)° in the two independent mol­ecules. The dichloro­phenyl and indole rings are twisted away from the bipyridine ring by 64.32 (5) and 18.46 (4)°, respectively in the first molecule and by 51.0 (1) and 27.99 (5)°, respectively in the second molecule. The crystal packing is stabilized by C—H⋯N, C—H⋯Cl, N—H⋯N and C—H⋯π inter­actions.
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spelling pubmed-29776882010-12-30 4-(2,4-Dichloro­phen­yl)-6-(1H-indol-3-yl)-2,2′-bipyridine-5-carbonitrile Ramesh, P. Sundaresan, S. S. Thirumurugan, P. Perumal, Paramasivan T. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(14)Cl(2)N(4), crystallizes with two independent mol­ecules in the asymmetric unit. The two pyridine rings are almost coplanar, making dihedral angles of 3.2 (1) and 8.6 (1)° in the two independent mol­ecules. The dichloro­phenyl and indole rings are twisted away from the bipyridine ring by 64.32 (5) and 18.46 (4)°, respectively in the first molecule and by 51.0 (1) and 27.99 (5)°, respectively in the second molecule. The crystal packing is stabilized by C—H⋯N, C—H⋯Cl, N—H⋯N and C—H⋯π inter­actions. International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977688/ /pubmed/21584031 http://dx.doi.org/10.1107/S1600536809012392 Text en © Ramesh et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ramesh, P.
Sundaresan, S. S.
Thirumurugan, P.
Perumal, Paramasivan T.
Ponnuswamy, M. N.
4-(2,4-Dichloro­phen­yl)-6-(1H-indol-3-yl)-2,2′-bipyridine-5-carbonitrile
title 4-(2,4-Dichloro­phen­yl)-6-(1H-indol-3-yl)-2,2′-bipyridine-5-carbonitrile
title_full 4-(2,4-Dichloro­phen­yl)-6-(1H-indol-3-yl)-2,2′-bipyridine-5-carbonitrile
title_fullStr 4-(2,4-Dichloro­phen­yl)-6-(1H-indol-3-yl)-2,2′-bipyridine-5-carbonitrile
title_full_unstemmed 4-(2,4-Dichloro­phen­yl)-6-(1H-indol-3-yl)-2,2′-bipyridine-5-carbonitrile
title_short 4-(2,4-Dichloro­phen­yl)-6-(1H-indol-3-yl)-2,2′-bipyridine-5-carbonitrile
title_sort 4-(2,4-dichloro­phen­yl)-6-(1h-indol-3-yl)-2,2′-bipyridine-5-carbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977688/
https://www.ncbi.nlm.nih.gov/pubmed/21584031
http://dx.doi.org/10.1107/S1600536809012392
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AT thirumuruganp 424dichlorophenyl61hindol3yl22bipyridine5carbonitrile
AT perumalparamasivant 424dichlorophenyl61hindol3yl22bipyridine5carbonitrile
AT ponnuswamymn 424dichlorophenyl61hindol3yl22bipyridine5carbonitrile

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