Redetermination of methyl 3,4-O-isopropyl­idene-β-D-fucopyran­oside monohydrate

In the title compound, C(10)H(18)O(5)·H(2)O, the fucopyran­oside ring adopts a chair conformation. The crystal packing is stabilized by inter­molecular O—H⋯O and C—H⋯O hydrogen bonds together with intra­molecular O⋯O [2.2936 (8) Å] and inter­molecular O⋯O [2.7140 (8)–2.829 (3) Å] short contacts. The...

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Autores principales: Fun, Hoong-Kun, Jebas, Samuel Robinson, Rai, Sankappa, Shetty, Prakash, Isloor, Arun M
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977692/
https://www.ncbi.nlm.nih.gov/pubmed/21583828
http://dx.doi.org/10.1107/S1600536809012689
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author Fun, Hoong-Kun
Jebas, Samuel Robinson
Rai, Sankappa
Shetty, Prakash
Isloor, Arun M
author_facet Fun, Hoong-Kun
Jebas, Samuel Robinson
Rai, Sankappa
Shetty, Prakash
Isloor, Arun M
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(10)H(18)O(5)·H(2)O, the fucopyran­oside ring adopts a chair conformation. The crystal packing is stabilized by inter­molecular O—H⋯O and C—H⋯O hydrogen bonds together with intra­molecular O⋯O [2.2936 (8) Å] and inter­molecular O⋯O [2.7140 (8)–2.829 (3) Å] short contacts. The mol­ecules are linked together to form an infinite chain along the a axis. This structure has been solved previously but with no R-values [Spiers (1931). Z. Kristallogr. Kristallgeom. Kristallphys. Kristallchem. 78, 101].
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spelling pubmed-29776922010-12-30 Redetermination of methyl 3,4-O-isopropyl­idene-β-D-fucopyran­oside monohydrate Fun, Hoong-Kun Jebas, Samuel Robinson Rai, Sankappa Shetty, Prakash Isloor, Arun M Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(18)O(5)·H(2)O, the fucopyran­oside ring adopts a chair conformation. The crystal packing is stabilized by inter­molecular O—H⋯O and C—H⋯O hydrogen bonds together with intra­molecular O⋯O [2.2936 (8) Å] and inter­molecular O⋯O [2.7140 (8)–2.829 (3) Å] short contacts. The mol­ecules are linked together to form an infinite chain along the a axis. This structure has been solved previously but with no R-values [Spiers (1931). Z. Kristallogr. Kristallgeom. Kristallphys. Kristallchem. 78, 101]. International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977692/ /pubmed/21583828 http://dx.doi.org/10.1107/S1600536809012689 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Jebas, Samuel Robinson
Rai, Sankappa
Shetty, Prakash
Isloor, Arun M
Redetermination of methyl 3,4-O-isopropyl­idene-β-D-fucopyran­oside monohydrate
title Redetermination of methyl 3,4-O-isopropyl­idene-β-D-fucopyran­oside monohydrate
title_full Redetermination of methyl 3,4-O-isopropyl­idene-β-D-fucopyran­oside monohydrate
title_fullStr Redetermination of methyl 3,4-O-isopropyl­idene-β-D-fucopyran­oside monohydrate
title_full_unstemmed Redetermination of methyl 3,4-O-isopropyl­idene-β-D-fucopyran­oside monohydrate
title_short Redetermination of methyl 3,4-O-isopropyl­idene-β-D-fucopyran­oside monohydrate
title_sort redetermination of methyl 3,4-o-isopropyl­idene-β-d-fucopyran­oside monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977692/
https://www.ncbi.nlm.nih.gov/pubmed/21583828
http://dx.doi.org/10.1107/S1600536809012689
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