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Piperazinediium dioxamate

The title compound, C(4)H(12)N(2) (2+)·2C(2)H(2)NO(3) (−), contains a network of doubly protanated piperazinium cations (lying about centres of inversion) and dioxamate anions. The piperazinium dication adopts a typical chair conformation. The crystal structure is stabilized by cation–to–anion N—H⋯O...

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Detalles Bibliográficos
Autores principales: Murugavel, S., Selvakumar, R., Govindarajan, S., Kannan, P. S., SubbiahPandi, A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977693/
https://www.ncbi.nlm.nih.gov/pubmed/21583829
http://dx.doi.org/10.1107/S1600536809012513
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author Murugavel, S.
Selvakumar, R.
Govindarajan, S.
Kannan, P. S.
SubbiahPandi, A.
author_facet Murugavel, S.
Selvakumar, R.
Govindarajan, S.
Kannan, P. S.
SubbiahPandi, A.
author_sort Murugavel, S.
collection PubMed
description The title compound, C(4)H(12)N(2) (2+)·2C(2)H(2)NO(3) (−), contains a network of doubly protanated piperazinium cations (lying about centres of inversion) and dioxamate anions. The piperazinium dication adopts a typical chair conformation. The crystal structure is stabilized by cation–to–anion N—H⋯O and anion–to–anion N—H⋯O hydrogen bonds.
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spelling pubmed-29776932010-12-30 Piperazinediium dioxamate Murugavel, S. Selvakumar, R. Govindarajan, S. Kannan, P. S. SubbiahPandi, A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(4)H(12)N(2) (2+)·2C(2)H(2)NO(3) (−), contains a network of doubly protanated piperazinium cations (lying about centres of inversion) and dioxamate anions. The piperazinium dication adopts a typical chair conformation. The crystal structure is stabilized by cation–to–anion N—H⋯O and anion–to–anion N—H⋯O hydrogen bonds. International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977693/ /pubmed/21583829 http://dx.doi.org/10.1107/S1600536809012513 Text en © Murugavel et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Murugavel, S.
Selvakumar, R.
Govindarajan, S.
Kannan, P. S.
SubbiahPandi, A.
Piperazinediium dioxamate
title Piperazinediium dioxamate
title_full Piperazinediium dioxamate
title_fullStr Piperazinediium dioxamate
title_full_unstemmed Piperazinediium dioxamate
title_short Piperazinediium dioxamate
title_sort piperazinediium dioxamate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977693/
https://www.ncbi.nlm.nih.gov/pubmed/21583829
http://dx.doi.org/10.1107/S1600536809012513
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AT subbiahpandia piperazinediiumdioxamate