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2-Benzoylmethyl-4-[(2-benzylidene­ethylidene)amino]-5-(2-thienylmethyl)-2H-1,2,4-triazol-3(4H)-one

In the mol­ecule of the title compound, C(24)H(20)N(4)O(2)S, the dihedral angle between the triazole and thio­phene rings is 66.80 (4)° and the dihedral angle between the two benzene rings is 63.37 (4)°. An intra­molecular C—H⋯O inter­action results in the formation of a six-membered ring. A π⋯π con...

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Detalles Bibliográficos
Autores principales: Ustabaş, Reşat, Ünver, Yasemin, Suleymanoğlu, Nevin, Çoruh, Ufuk, Sancak, Kemal
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977695/
https://www.ncbi.nlm.nih.gov/pubmed/21583831
http://dx.doi.org/10.1107/S1600536809012719
Descripción
Sumario:In the mol­ecule of the title compound, C(24)H(20)N(4)O(2)S, the dihedral angle between the triazole and thio­phene rings is 66.80 (4)° and the dihedral angle between the two benzene rings is 63.37 (4)°. An intra­molecular C—H⋯O inter­action results in the formation of a six-membered ring. A π⋯π contact between the benzene rings, [centroid–centroid distance = 3.918 (2) Å] may stabilize the structure. Weak C—H⋯π inter­actions are also present. The S, C and H atoms of the thiophene ring are disordered over two positions and were refined with occupancies of 0.654 (3) and 0.346 (3).