2-Benzoylmethyl-4-[(2-benzylidene­ethylidene)amino]-5-(2-thienylmethyl)-2H-1,2,4-triazol-3(4H)-one

In the mol­ecule of the title compound, C(24)H(20)N(4)O(2)S, the dihedral angle between the triazole and thio­phene rings is 66.80 (4)° and the dihedral angle between the two benzene rings is 63.37 (4)°. An intra­molecular C—H⋯O inter­action results in the formation of a six-membered ring. A π⋯π con...

Descripción completa

Detalles Bibliográficos
Autores principales: Ustabaş, Reşat, Ünver, Yasemin, Suleymanoğlu, Nevin, Çoruh, Ufuk, Sancak, Kemal
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977695/
https://www.ncbi.nlm.nih.gov/pubmed/21583831
http://dx.doi.org/10.1107/S1600536809012719
_version_ 1782191166125506560
author Ustabaş, Reşat
Ünver, Yasemin
Suleymanoğlu, Nevin
Çoruh, Ufuk
Sancak, Kemal
author_facet Ustabaş, Reşat
Ünver, Yasemin
Suleymanoğlu, Nevin
Çoruh, Ufuk
Sancak, Kemal
author_sort Ustabaş, Reşat
collection PubMed
description In the mol­ecule of the title compound, C(24)H(20)N(4)O(2)S, the dihedral angle between the triazole and thio­phene rings is 66.80 (4)° and the dihedral angle between the two benzene rings is 63.37 (4)°. An intra­molecular C—H⋯O inter­action results in the formation of a six-membered ring. A π⋯π contact between the benzene rings, [centroid–centroid distance = 3.918 (2) Å] may stabilize the structure. Weak C—H⋯π inter­actions are also present. The S, C and H atoms of the thiophene ring are disordered over two positions and were refined with occupancies of 0.654 (3) and 0.346 (3).
format Text
id pubmed-2977695
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29776952010-12-30 2-Benzoylmethyl-4-[(2-benzylidene­ethylidene)amino]-5-(2-thienylmethyl)-2H-1,2,4-triazol-3(4H)-one Ustabaş, Reşat Ünver, Yasemin Suleymanoğlu, Nevin Çoruh, Ufuk Sancak, Kemal Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(24)H(20)N(4)O(2)S, the dihedral angle between the triazole and thio­phene rings is 66.80 (4)° and the dihedral angle between the two benzene rings is 63.37 (4)°. An intra­molecular C—H⋯O inter­action results in the formation of a six-membered ring. A π⋯π contact between the benzene rings, [centroid–centroid distance = 3.918 (2) Å] may stabilize the structure. Weak C—H⋯π inter­actions are also present. The S, C and H atoms of the thiophene ring are disordered over two positions and were refined with occupancies of 0.654 (3) and 0.346 (3). International Union of Crystallography 2009-04-08 /pmc/articles/PMC2977695/ /pubmed/21583831 http://dx.doi.org/10.1107/S1600536809012719 Text en © Ustabaş et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ustabaş, Reşat
Ünver, Yasemin
Suleymanoğlu, Nevin
Çoruh, Ufuk
Sancak, Kemal
2-Benzoylmethyl-4-[(2-benzylidene­ethylidene)amino]-5-(2-thienylmethyl)-2H-1,2,4-triazol-3(4H)-one
title 2-Benzoylmethyl-4-[(2-benzylidene­ethylidene)amino]-5-(2-thienylmethyl)-2H-1,2,4-triazol-3(4H)-one
title_full 2-Benzoylmethyl-4-[(2-benzylidene­ethylidene)amino]-5-(2-thienylmethyl)-2H-1,2,4-triazol-3(4H)-one
title_fullStr 2-Benzoylmethyl-4-[(2-benzylidene­ethylidene)amino]-5-(2-thienylmethyl)-2H-1,2,4-triazol-3(4H)-one
title_full_unstemmed 2-Benzoylmethyl-4-[(2-benzylidene­ethylidene)amino]-5-(2-thienylmethyl)-2H-1,2,4-triazol-3(4H)-one
title_short 2-Benzoylmethyl-4-[(2-benzylidene­ethylidene)amino]-5-(2-thienylmethyl)-2H-1,2,4-triazol-3(4H)-one
title_sort 2-benzoylmethyl-4-[(2-benzylidene­ethylidene)amino]-5-(2-thienylmethyl)-2h-1,2,4-triazol-3(4h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977695/
https://www.ncbi.nlm.nih.gov/pubmed/21583831
http://dx.doi.org/10.1107/S1600536809012719
work_keys_str_mv AT ustabasresat 2benzoylmethyl42benzylideneethylideneamino52thienylmethyl2h124triazol34hone
AT unveryasemin 2benzoylmethyl42benzylideneethylideneamino52thienylmethyl2h124triazol34hone
AT suleymanoglunevin 2benzoylmethyl42benzylideneethylideneamino52thienylmethyl2h124triazol34hone
AT coruhufuk 2benzoylmethyl42benzylideneethylideneamino52thienylmethyl2h124triazol34hone
AT sancakkemal 2benzoylmethyl42benzylideneethylideneamino52thienylmethyl2h124triazol34hone

Ejemplares similares