1-Furoyl-3-[3-(trifluoro­meth­yl)phen­yl]thio­urea

The title compound, C(13)H(9)F(3)N(2)O(2)S, crystallizes with two independent mol­ecules in the asymmetric unit. The central thio­urea core is roughly coplanar with the furan and benzene rings, showing O—C—N—C(S) torsion angles of 2.3 (4) and −11.4 (2)° and (S)C—N—C—C torsion angles of −2.4 (4) and...

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Detalles Bibliográficos
Autores principales: Theodoro, Jahyr E., Estévez-Hernández, O., Ellena, J., Duque, J., Corrêa, Rodrigo S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977699/
https://www.ncbi.nlm.nih.gov/pubmed/21583835
http://dx.doi.org/10.1107/S1600536809013038
Descripción
Sumario:The title compound, C(13)H(9)F(3)N(2)O(2)S, crystallizes with two independent mol­ecules in the asymmetric unit. The central thio­urea core is roughly coplanar with the furan and benzene rings, showing O—C—N—C(S) torsion angles of 2.3 (4) and −11.4 (2)° and (S)C—N—C—C torsion angles of −2.4 (4) and −28.8 (4)°, respectively, in the two independent mol­ecules. The trans–cis geometry of the thio­urea fragment is stabilized by an intra­molecular N—H⋯O hydrogen bond between the H atom of the cis thio­amide and the carbonyl O atom. In the crystal structure, inter­molecular N—H⋯S hydrogen bonds form centrosymmetric dimers extending along the b axis.

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