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2,6-Bis(1H-benzimidazol­-2-yl)pyridine methanol trisolvate

In the title compound, C(19)H(13)N(5)·3CH(4)O, the 2,6-bis­(2-benzimidazol­yl)pyridine mol­ecule is essentially planar with an r.m.s. deviation for all non-H atoms of 0.185 Å. The crystal structure is stabilized by inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds and weak π⋯π stacking inter­act...

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Detalles Bibliográficos
Autores principales: Chen, Ying, Guo, Jixi, Huang, Xingcai, Yun, Ruirui, Wu, Huilu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977700/
https://www.ncbi.nlm.nih.gov/pubmed/21583836
http://dx.doi.org/10.1107/S1600536809012574
Descripción
Sumario:In the title compound, C(19)H(13)N(5)·3CH(4)O, the 2,6-bis­(2-benzimidazol­yl)pyridine mol­ecule is essentially planar with an r.m.s. deviation for all non-H atoms of 0.185 Å. The crystal structure is stabilized by inter­molecular O—H⋯O, O—H⋯N and N—H⋯O hydrogen bonds and weak π⋯π stacking inter­actions with centroid–centroid distances of 3.6675 (16) and 3.6891 (15) Å. The atoms of one of the methanol solvent molecules are disordered over two sites with refined occupancies of 0.606(8) and 0.394(8).