2-Chloro-N-(3,4-dimethyl­phen­yl)acetamide

The conformation of the C=O bond in the structure of the title compound, C(10)H(12)ClNO, is anti to the N—H bond and to the methyl­ene H atoms in the side chain in both the independent mol­ecules comprising the asymmetric unit. However, the conformation of the N—H bond is syn to the meta-methyl subs...

Descripción completa

Detalles Bibliográficos
Autores principales: Gowda, B. Thimme, Foro, Sabine, Terao, Hiromitsu, Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977707/
https://www.ncbi.nlm.nih.gov/pubmed/21583843
http://dx.doi.org/10.1107/S1600536809013051
_version_ 1782191169062567936
author Gowda, B. Thimme
Foro, Sabine
Terao, Hiromitsu
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Terao, Hiromitsu
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description The conformation of the C=O bond in the structure of the title compound, C(10)H(12)ClNO, is anti to the N—H bond and to the methyl­ene H atoms in the side chain in both the independent mol­ecules comprising the asymmetric unit. However, the conformation of the N—H bond is syn to the meta-methyl substituent in the aromatic ring of one of the mol­ecules and anti in the other mol­ecule. The two independent mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonding into chains parallel to the b axis.
format Text
id pubmed-2977707
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29777072010-12-30 2-Chloro-N-(3,4-dimethyl­phen­yl)acetamide Gowda, B. Thimme Foro, Sabine Terao, Hiromitsu Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers The conformation of the C=O bond in the structure of the title compound, C(10)H(12)ClNO, is anti to the N—H bond and to the methyl­ene H atoms in the side chain in both the independent mol­ecules comprising the asymmetric unit. However, the conformation of the N—H bond is syn to the meta-methyl substituent in the aromatic ring of one of the mol­ecules and anti in the other mol­ecule. The two independent mol­ecules are linked through inter­molecular N—H⋯O hydrogen bonding into chains parallel to the b axis. International Union of Crystallography 2009-04-10 /pmc/articles/PMC2977707/ /pubmed/21583843 http://dx.doi.org/10.1107/S1600536809013051 Text en © Gowda et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Terao, Hiromitsu
Fuess, Hartmut
2-Chloro-N-(3,4-dimethyl­phen­yl)acetamide
title 2-Chloro-N-(3,4-dimethyl­phen­yl)acetamide
title_full 2-Chloro-N-(3,4-dimethyl­phen­yl)acetamide
title_fullStr 2-Chloro-N-(3,4-dimethyl­phen­yl)acetamide
title_full_unstemmed 2-Chloro-N-(3,4-dimethyl­phen­yl)acetamide
title_short 2-Chloro-N-(3,4-dimethyl­phen­yl)acetamide
title_sort 2-chloro-n-(3,4-dimethyl­phen­yl)acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977707/
https://www.ncbi.nlm.nih.gov/pubmed/21583843
http://dx.doi.org/10.1107/S1600536809013051
work_keys_str_mv AT gowdabthimme 2chloron34dimethylphenylacetamide
AT forosabine 2chloron34dimethylphenylacetamide
AT teraohiromitsu 2chloron34dimethylphenylacetamide
AT fuesshartmut 2chloron34dimethylphenylacetamide

Ejemplares similares