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2-Hydroxy-3-nitro-N-phenylbenzamide
The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two crystallographically independent molecules. The aromatic rings are oriented at dihedral angles of 24.39 (3) and 7.47 (3)° in the two molecules and intramolecular N—H⋯O and O—H⋯O hydrogen bonds result in the formation of t...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977725/ https://www.ncbi.nlm.nih.gov/pubmed/21583861 http://dx.doi.org/10.1107/S1600536809013063 |
Sumario: | The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two crystallographically independent molecules. The aromatic rings are oriented at dihedral angles of 24.39 (3) and 7.47 (3)° in the two molecules and intramolecular N—H⋯O and O—H⋯O hydrogen bonds result in the formation of two planar six-membered rings. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link the molecules into chains, forming R (2) (2)(10) ring motifs. Weak π–π contacts between the benzene and phenyl rings [centroid–centroid distance = 3.955 (3) Å] may further stabilize the structure. |
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