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2-Hydroxy-3-nitro-N-phenylbenzamide
The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two crystallographically independent molecules. The aromatic rings are oriented at dihedral angles of 24.39 (3) and 7.47 (3)° in the two molecules and intramolecular N—H⋯O and O—H⋯O hydrogen bonds result in the formation of t...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977725/ https://www.ncbi.nlm.nih.gov/pubmed/21583861 http://dx.doi.org/10.1107/S1600536809013063 |
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author | Raza, Abdul Rauf Danish, Muhammad Tahir, M. Nawaz Nisar, Bushra Park, Gyungse |
author_facet | Raza, Abdul Rauf Danish, Muhammad Tahir, M. Nawaz Nisar, Bushra Park, Gyungse |
author_sort | Raza, Abdul Rauf |
collection | PubMed |
description | The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two crystallographically independent molecules. The aromatic rings are oriented at dihedral angles of 24.39 (3) and 7.47 (3)° in the two molecules and intramolecular N—H⋯O and O—H⋯O hydrogen bonds result in the formation of two planar six-membered rings. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link the molecules into chains, forming R (2) (2)(10) ring motifs. Weak π–π contacts between the benzene and phenyl rings [centroid–centroid distance = 3.955 (3) Å] may further stabilize the structure. |
format | Text |
id | pubmed-2977725 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29777252010-12-30 2-Hydroxy-3-nitro-N-phenylbenzamide Raza, Abdul Rauf Danish, Muhammad Tahir, M. Nawaz Nisar, Bushra Park, Gyungse Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two crystallographically independent molecules. The aromatic rings are oriented at dihedral angles of 24.39 (3) and 7.47 (3)° in the two molecules and intramolecular N—H⋯O and O—H⋯O hydrogen bonds result in the formation of two planar six-membered rings. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link the molecules into chains, forming R (2) (2)(10) ring motifs. Weak π–π contacts between the benzene and phenyl rings [centroid–centroid distance = 3.955 (3) Å] may further stabilize the structure. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977725/ /pubmed/21583861 http://dx.doi.org/10.1107/S1600536809013063 Text en © Raza et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Raza, Abdul Rauf Danish, Muhammad Tahir, M. Nawaz Nisar, Bushra Park, Gyungse 2-Hydroxy-3-nitro-N-phenylbenzamide |
title | 2-Hydroxy-3-nitro-N-phenylbenzamide |
title_full | 2-Hydroxy-3-nitro-N-phenylbenzamide |
title_fullStr | 2-Hydroxy-3-nitro-N-phenylbenzamide |
title_full_unstemmed | 2-Hydroxy-3-nitro-N-phenylbenzamide |
title_short | 2-Hydroxy-3-nitro-N-phenylbenzamide |
title_sort | 2-hydroxy-3-nitro-n-phenylbenzamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977725/ https://www.ncbi.nlm.nih.gov/pubmed/21583861 http://dx.doi.org/10.1107/S1600536809013063 |
work_keys_str_mv | AT razaabdulrauf 2hydroxy3nitronphenylbenzamide AT danishmuhammad 2hydroxy3nitronphenylbenzamide AT tahirmnawaz 2hydroxy3nitronphenylbenzamide AT nisarbushra 2hydroxy3nitronphenylbenzamide AT parkgyungse 2hydroxy3nitronphenylbenzamide |