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2-Hydr­oxy-3-nitro-N-phenyl­benzamide

The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two crystallographically independent mol­ecules. The aromatic rings are oriented at dihedral angles of 24.39 (3) and 7.47 (3)° in the two mol­ecules and intra­molecular N—H⋯O and O—H⋯O hydrogen bonds result in the formation of t...

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Detalles Bibliográficos
Autores principales: Raza, Abdul Rauf, Danish, Muhammad, Tahir, M. Nawaz, Nisar, Bushra, Park, Gyungse
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977725/
https://www.ncbi.nlm.nih.gov/pubmed/21583861
http://dx.doi.org/10.1107/S1600536809013063
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author Raza, Abdul Rauf
Danish, Muhammad
Tahir, M. Nawaz
Nisar, Bushra
Park, Gyungse
author_facet Raza, Abdul Rauf
Danish, Muhammad
Tahir, M. Nawaz
Nisar, Bushra
Park, Gyungse
author_sort Raza, Abdul Rauf
collection PubMed
description The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two crystallographically independent mol­ecules. The aromatic rings are oriented at dihedral angles of 24.39 (3) and 7.47 (3)° in the two mol­ecules and intra­molecular N—H⋯O and O—H⋯O hydrogen bonds result in the formation of two planar six-membered rings. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into chains, forming R (2) (2)(10) ring motifs. Weak π–π contacts between the benzene and phenyl rings [centroid–centroid distance = 3.955 (3) Å] may further stabilize the structure.
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spelling pubmed-29777252010-12-30 2-Hydr­oxy-3-nitro-N-phenyl­benzamide Raza, Abdul Rauf Danish, Muhammad Tahir, M. Nawaz Nisar, Bushra Park, Gyungse Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(13)H(10)N(2)O(4), contains two crystallographically independent mol­ecules. The aromatic rings are oriented at dihedral angles of 24.39 (3) and 7.47 (3)° in the two mol­ecules and intra­molecular N—H⋯O and O—H⋯O hydrogen bonds result in the formation of two planar six-membered rings. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into chains, forming R (2) (2)(10) ring motifs. Weak π–π contacts between the benzene and phenyl rings [centroid–centroid distance = 3.955 (3) Å] may further stabilize the structure. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977725/ /pubmed/21583861 http://dx.doi.org/10.1107/S1600536809013063 Text en © Raza et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Raza, Abdul Rauf
Danish, Muhammad
Tahir, M. Nawaz
Nisar, Bushra
Park, Gyungse
2-Hydr­oxy-3-nitro-N-phenyl­benzamide
title 2-Hydr­oxy-3-nitro-N-phenyl­benzamide
title_full 2-Hydr­oxy-3-nitro-N-phenyl­benzamide
title_fullStr 2-Hydr­oxy-3-nitro-N-phenyl­benzamide
title_full_unstemmed 2-Hydr­oxy-3-nitro-N-phenyl­benzamide
title_short 2-Hydr­oxy-3-nitro-N-phenyl­benzamide
title_sort 2-hydr­oxy-3-nitro-n-phenyl­benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977725/
https://www.ncbi.nlm.nih.gov/pubmed/21583861
http://dx.doi.org/10.1107/S1600536809013063
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