Tetra­ethyl­ammonium 12-phenyl­ethynylcarba-closo-dodeca­borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)]

The asymmetric unit of the title compound, C(8)H(20)N(+)·C(9)H(16)B(11) (−) or [Et(4)N][12-PhCC-closo-CB(11)H(11)], consists of one cation and one anion. The [12-PhCC-closo-CB(11)H(11)](−) anion is close to possessing a non-crystallographic plane of mirror symmetry with a nearly linear B—C C—C group...

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Detalles Bibliográficos
Autores principales: Finze, Maik, Reiss, Guido J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977730/
https://www.ncbi.nlm.nih.gov/pubmed/21583866
http://dx.doi.org/10.1107/S1600536809013300
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author Finze, Maik
Reiss, Guido J.
author_facet Finze, Maik
Reiss, Guido J.
author_sort Finze, Maik
collection PubMed
description The asymmetric unit of the title compound, C(8)H(20)N(+)·C(9)H(16)B(11) (−) or [Et(4)N][12-PhCC-closo-CB(11)H(11)], consists of one cation and one anion. The [12-PhCC-closo-CB(11)H(11)](−) anion is close to possessing a non-crystallographic plane of mirror symmetry with a nearly linear B—C C—C group, with B—C C and C C—C angles of 177.15 (16) and 176.64 (17)°, respectively.
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spelling pubmed-29777302010-12-30 Tetra­ethyl­ammonium 12-phenyl­ethynylcarba-closo-dodeca­borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)] Finze, Maik Reiss, Guido J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(8)H(20)N(+)·C(9)H(16)B(11) (−) or [Et(4)N][12-PhCC-closo-CB(11)H(11)], consists of one cation and one anion. The [12-PhCC-closo-CB(11)H(11)](−) anion is close to possessing a non-crystallographic plane of mirror symmetry with a nearly linear B—C C—C group, with B—C C and C C—C angles of 177.15 (16) and 176.64 (17)°, respectively. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977730/ /pubmed/21583866 http://dx.doi.org/10.1107/S1600536809013300 Text en © Finze and Reiss 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Finze, Maik
Reiss, Guido J.
Tetra­ethyl­ammonium 12-phenyl­ethynylcarba-closo-dodeca­borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)]
title Tetra­ethyl­ammonium 12-phenyl­ethynylcarba-closo-dodeca­borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)]
title_full Tetra­ethyl­ammonium 12-phenyl­ethynylcarba-closo-dodeca­borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)]
title_fullStr Tetra­ethyl­ammonium 12-phenyl­ethynylcarba-closo-dodeca­borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)]
title_full_unstemmed Tetra­ethyl­ammonium 12-phenyl­ethynylcarba-closo-dodeca­borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)]
title_short Tetra­ethyl­ammonium 12-phenyl­ethynylcarba-closo-dodeca­borate, [Et(4)N][12-PhCC-closo-CB(11)H(11)]
title_sort tetra­ethyl­ammonium 12-phenyl­ethynylcarba-closo-dodeca­borate, [et(4)n][12-phcc-closo-cb(11)h(11)]
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977730/
https://www.ncbi.nlm.nih.gov/pubmed/21583866
http://dx.doi.org/10.1107/S1600536809013300
work_keys_str_mv AT finzemaik tetraethylammonium12phenylethynylcarbaclosododecaborateet4n12phccclosocb11h11
AT reissguidoj tetraethylammonium12phenylethynylcarbaclosododecaborateet4n12phccclosocb11h11

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