Cargando…
Di-4-pyridyl disulfide–isophthalic acid (1/1)
In the title 1:1 cocrystal, C(10)H(8)N(2)S(2)·C(8)H(6)O(4), the asymmetric unit contains an isophthalic acid molecule and a 4,4′-dipyridyl disulfide molecule. The two carboxyl groups of isophthalic acid interact with neighbouring 4,4′-dipyridyl disulfide molecules through O—H⋯N hydrogen bonds, f...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977736/ https://www.ncbi.nlm.nih.gov/pubmed/21583872 http://dx.doi.org/10.1107/S1600536809013397 |
Sumario: | In the title 1:1 cocrystal, C(10)H(8)N(2)S(2)·C(8)H(6)O(4), the asymmetric unit contains an isophthalic acid molecule and a 4,4′-dipyridyl disulfide molecule. The two carboxyl groups of isophthalic acid interact with neighbouring 4,4′-dipyridyl disulfide molecules through O—H⋯N hydrogen bonds, forming a one-dimensional zigzag chain. Neighbouring chains are linked to each other via π–π stacking interactions between the pyridyl rings of adjacent 4,4′-dipyridyl disulfide molecules [centroid-centroid distance = 3.7346 (6) Å], resulting in a layered motif. The dihedral angle between pyridine rings of 84.13 (7)° and the C—S—S—C torsion angle of 91.95 (1)° confirm the gauche conformation of 4,4′-dipyridyl disulfide. |
---|