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Di-4-pyridyl disulfide–isophthalic acid (1/1)

In the title 1:1 cocrystal, C(10)H(8)N(2)S(2)·C(8)H(6)O(4), the asymmetric unit contains an isophthalic acid mol­ecule and a 4,4′-dipyridyl disulfide mol­ecule. The two carboxyl groups of isophthalic acid inter­act with neighbouring 4,4′-dipyridyl disulfide mol­ecules through O—H⋯N hydrogen bonds, f...

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Detalles Bibliográficos
Autores principales: Wang, Dan-Jun, Zhao, Jun-Ming, Zhang, Jie, Lin, Jian-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977736/
https://www.ncbi.nlm.nih.gov/pubmed/21583872
http://dx.doi.org/10.1107/S1600536809013397
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author Wang, Dan-Jun
Zhao, Jun-Ming
Zhang, Jie
Lin, Jian-Li
author_facet Wang, Dan-Jun
Zhao, Jun-Ming
Zhang, Jie
Lin, Jian-Li
author_sort Wang, Dan-Jun
collection PubMed
description In the title 1:1 cocrystal, C(10)H(8)N(2)S(2)·C(8)H(6)O(4), the asymmetric unit contains an isophthalic acid mol­ecule and a 4,4′-dipyridyl disulfide mol­ecule. The two carboxyl groups of isophthalic acid inter­act with neighbouring 4,4′-dipyridyl disulfide mol­ecules through O—H⋯N hydrogen bonds, forming a one-dimensional zigzag chain. Neighbouring chains are linked to each other via π–π stacking inter­actions between the pyridyl rings of adjacent 4,4′-dipyridyl disulfide mol­ecules [centroid-centroid distance = 3.7346 (6) Å], resulting in a layered motif. The dihedral angle between pyridine rings of 84.13 (7)° and the C—S—S—C torsion angle of 91.95 (1)° confirm the gauche conformation of 4,4′-dipyridyl disulfide.
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spelling pubmed-29777362010-12-30 Di-4-pyridyl disulfide–isophthalic acid (1/1) Wang, Dan-Jun Zhao, Jun-Ming Zhang, Jie Lin, Jian-Li Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title 1:1 cocrystal, C(10)H(8)N(2)S(2)·C(8)H(6)O(4), the asymmetric unit contains an isophthalic acid mol­ecule and a 4,4′-dipyridyl disulfide mol­ecule. The two carboxyl groups of isophthalic acid inter­act with neighbouring 4,4′-dipyridyl disulfide mol­ecules through O—H⋯N hydrogen bonds, forming a one-dimensional zigzag chain. Neighbouring chains are linked to each other via π–π stacking inter­actions between the pyridyl rings of adjacent 4,4′-dipyridyl disulfide mol­ecules [centroid-centroid distance = 3.7346 (6) Å], resulting in a layered motif. The dihedral angle between pyridine rings of 84.13 (7)° and the C—S—S—C torsion angle of 91.95 (1)° confirm the gauche conformation of 4,4′-dipyridyl disulfide. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977736/ /pubmed/21583872 http://dx.doi.org/10.1107/S1600536809013397 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Dan-Jun
Zhao, Jun-Ming
Zhang, Jie
Lin, Jian-Li
Di-4-pyridyl disulfide–isophthalic acid (1/1)
title Di-4-pyridyl disulfide–isophthalic acid (1/1)
title_full Di-4-pyridyl disulfide–isophthalic acid (1/1)
title_fullStr Di-4-pyridyl disulfide–isophthalic acid (1/1)
title_full_unstemmed Di-4-pyridyl disulfide–isophthalic acid (1/1)
title_short Di-4-pyridyl disulfide–isophthalic acid (1/1)
title_sort di-4-pyridyl disulfide–isophthalic acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977736/
https://www.ncbi.nlm.nih.gov/pubmed/21583872
http://dx.doi.org/10.1107/S1600536809013397
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