Bis(2-amino-4,5-dimethyl­anilinium chloride) 4,5-dimethyl­benz­ene-1,2-diamine monohydrate

The title compound, 2C(8)H(13)N(2) (+)·2Cl(−)·C(8)H(12)N(2)·H(2)O, is a hydrated 2:1 cocrystal of the 2-amino-4,5-dimethyl­anilinium chloride salt and the 4,5-dimethyl­benz­ene-1,2-diamine free base. An intra­molecular N—H⋯N hydrogen bond occurs in one of the organic mol­ecules. In the crystal struc...

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Detalles Bibliográficos
Autor principal: Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977749/
https://www.ncbi.nlm.nih.gov/pubmed/21583885
http://dx.doi.org/10.1107/S1600536809013816
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author Ng, Seik Weng
author_facet Ng, Seik Weng
author_sort Ng, Seik Weng
collection PubMed
description The title compound, 2C(8)H(13)N(2) (+)·2Cl(−)·C(8)H(12)N(2)·H(2)O, is a hydrated 2:1 cocrystal of the 2-amino-4,5-dimethyl­anilinium chloride salt and the 4,5-dimethyl­benz­ene-1,2-diamine free base. An intra­molecular N—H⋯N hydrogen bond occurs in one of the organic mol­ecules. In the crystal structure, the components are linked by N—H⋯Cl, N—H⋯N, N—H⋯O and O—H⋯Cl hydrogen bonds into a layered motif.
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spelling pubmed-29777492010-12-30 Bis(2-amino-4,5-dimethyl­anilinium chloride) 4,5-dimethyl­benz­ene-1,2-diamine monohydrate Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, 2C(8)H(13)N(2) (+)·2Cl(−)·C(8)H(12)N(2)·H(2)O, is a hydrated 2:1 cocrystal of the 2-amino-4,5-dimethyl­anilinium chloride salt and the 4,5-dimethyl­benz­ene-1,2-diamine free base. An intra­molecular N—H⋯N hydrogen bond occurs in one of the organic mol­ecules. In the crystal structure, the components are linked by N—H⋯Cl, N—H⋯N, N—H⋯O and O—H⋯Cl hydrogen bonds into a layered motif. International Union of Crystallography 2009-04-18 /pmc/articles/PMC2977749/ /pubmed/21583885 http://dx.doi.org/10.1107/S1600536809013816 Text en © Seik Weng Ng 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ng, Seik Weng
Bis(2-amino-4,5-dimethyl­anilinium chloride) 4,5-dimethyl­benz­ene-1,2-diamine monohydrate
title Bis(2-amino-4,5-dimethyl­anilinium chloride) 4,5-dimethyl­benz­ene-1,2-diamine monohydrate
title_full Bis(2-amino-4,5-dimethyl­anilinium chloride) 4,5-dimethyl­benz­ene-1,2-diamine monohydrate
title_fullStr Bis(2-amino-4,5-dimethyl­anilinium chloride) 4,5-dimethyl­benz­ene-1,2-diamine monohydrate
title_full_unstemmed Bis(2-amino-4,5-dimethyl­anilinium chloride) 4,5-dimethyl­benz­ene-1,2-diamine monohydrate
title_short Bis(2-amino-4,5-dimethyl­anilinium chloride) 4,5-dimethyl­benz­ene-1,2-diamine monohydrate
title_sort bis(2-amino-4,5-dimethyl­anilinium chloride) 4,5-dimethyl­benz­ene-1,2-diamine monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977749/
https://www.ncbi.nlm.nih.gov/pubmed/21583885
http://dx.doi.org/10.1107/S1600536809013816
work_keys_str_mv AT ngseikweng bis2amino45dimethylaniliniumchloride45dimethylbenzene12diaminemonohydrate

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