P-[N-(Diphenyl­phospho­rothio­yl)iso­propyl­amino]-N-isopropyl-P-phenyl­thio­phosphinic amide

The title compound, C(24)H(30)N(2)P(2)S(2), was obtained by the reaction of Ph(2)PN(iPr)P(Ph)N(iPr)H with elemental sulfur in tetra­hydro­furan. In the solid state, intra­molecular N—H⋯S hydrogen bonding influences the mol­ecular conformation; a P—N—P—N torsion angle of 2.28 (9)° is observed. The tw...

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Detalles Bibliográficos
Autores principales: Peulecke, Normen, Aluri, Bhaskar R., Wöhl, Anina, Spannenberg, Anke, Al-Hazmi, Mohammed H.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977763/
https://www.ncbi.nlm.nih.gov/pubmed/21583899
http://dx.doi.org/10.1107/S1600536809014238
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author Peulecke, Normen
Aluri, Bhaskar R.
Wöhl, Anina
Spannenberg, Anke
Al-Hazmi, Mohammed H.
author_facet Peulecke, Normen
Aluri, Bhaskar R.
Wöhl, Anina
Spannenberg, Anke
Al-Hazmi, Mohammed H.
author_sort Peulecke, Normen
collection PubMed
description The title compound, C(24)H(30)N(2)P(2)S(2), was obtained by the reaction of Ph(2)PN(iPr)P(Ph)N(iPr)H with elemental sulfur in tetra­hydro­furan. In the solid state, intra­molecular N—H⋯S hydrogen bonding influences the mol­ecular conformation; a P—N—P—N torsion angle of 2.28 (9)° is observed. The two phenyl rings attached to one P atom form a dihedral angle of 74.02 (4)°.
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spelling pubmed-29777632010-12-30 P-[N-(Diphenyl­phospho­rothio­yl)iso­propyl­amino]-N-isopropyl-P-phenyl­thio­phosphinic amide Peulecke, Normen Aluri, Bhaskar R. Wöhl, Anina Spannenberg, Anke Al-Hazmi, Mohammed H. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(24)H(30)N(2)P(2)S(2), was obtained by the reaction of Ph(2)PN(iPr)P(Ph)N(iPr)H with elemental sulfur in tetra­hydro­furan. In the solid state, intra­molecular N—H⋯S hydrogen bonding influences the mol­ecular conformation; a P—N—P—N torsion angle of 2.28 (9)° is observed. The two phenyl rings attached to one P atom form a dihedral angle of 74.02 (4)°. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977763/ /pubmed/21583899 http://dx.doi.org/10.1107/S1600536809014238 Text en © Peulecke et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Peulecke, Normen
Aluri, Bhaskar R.
Wöhl, Anina
Spannenberg, Anke
Al-Hazmi, Mohammed H.
P-[N-(Diphenyl­phospho­rothio­yl)iso­propyl­amino]-N-isopropyl-P-phenyl­thio­phosphinic amide
title P-[N-(Diphenyl­phospho­rothio­yl)iso­propyl­amino]-N-isopropyl-P-phenyl­thio­phosphinic amide
title_full P-[N-(Diphenyl­phospho­rothio­yl)iso­propyl­amino]-N-isopropyl-P-phenyl­thio­phosphinic amide
title_fullStr P-[N-(Diphenyl­phospho­rothio­yl)iso­propyl­amino]-N-isopropyl-P-phenyl­thio­phosphinic amide
title_full_unstemmed P-[N-(Diphenyl­phospho­rothio­yl)iso­propyl­amino]-N-isopropyl-P-phenyl­thio­phosphinic amide
title_short P-[N-(Diphenyl­phospho­rothio­yl)iso­propyl­amino]-N-isopropyl-P-phenyl­thio­phosphinic amide
title_sort p-[n-(diphenyl­phospho­rothio­yl)iso­propyl­amino]-n-isopropyl-p-phenyl­thio­phosphinic amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977763/
https://www.ncbi.nlm.nih.gov/pubmed/21583899
http://dx.doi.org/10.1107/S1600536809014238
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