Methyl N′-[(E)-2-methoxy­benzyl­idene]­hydrazinecarboxyl­ate

The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit. The side chains in the two independent mol­ecules have slightly different orientations, with the C=N—N—C torsion angle being 169.19 (14)° in one of the mol­ecules and −179.86 (14)° in the oth...

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Detalles Bibliográficos
Autores principales: Lv, Lu-Ping, Yu, Wen-Bo, Lu, Zhong-Hao, Li, Wei-Wei, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977764/
https://www.ncbi.nlm.nih.gov/pubmed/21583900
http://dx.doi.org/10.1107/S1600536809014172
Descripción
Sumario:The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit. The side chains in the two independent mol­ecules have slightly different orientations, with the C=N—N—C torsion angle being 169.19 (14)° in one of the mol­ecules and −179.86 (14)° in the other. Each independent mol­ecule adopts a trans configuration with respect to the C=N bond. In the crystal structure, mol­ecules are linked into chains running along [001] by N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonds. In addition, an inter­molecular C—H⋯π inter­action is observed.

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