Methyl N′-[(E)-2-methoxy­benzyl­idene]­hydrazinecarboxyl­ate

The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit. The side chains in the two independent mol­ecules have slightly different orientations, with the C=N—N—C torsion angle being 169.19 (14)° in one of the mol­ecules and −179.86 (14)° in the oth...

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Autores principales: Lv, Lu-Ping, Yu, Wen-Bo, Lu, Zhong-Hao, Li, Wei-Wei, Hu, Xian-Chao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977764/
https://www.ncbi.nlm.nih.gov/pubmed/21583900
http://dx.doi.org/10.1107/S1600536809014172
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author Lv, Lu-Ping
Yu, Wen-Bo
Lu, Zhong-Hao
Li, Wei-Wei
Hu, Xian-Chao
author_facet Lv, Lu-Ping
Yu, Wen-Bo
Lu, Zhong-Hao
Li, Wei-Wei
Hu, Xian-Chao
author_sort Lv, Lu-Ping
collection PubMed
description The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit. The side chains in the two independent mol­ecules have slightly different orientations, with the C=N—N—C torsion angle being 169.19 (14)° in one of the mol­ecules and −179.86 (14)° in the other. Each independent mol­ecule adopts a trans configuration with respect to the C=N bond. In the crystal structure, mol­ecules are linked into chains running along [001] by N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonds. In addition, an inter­molecular C—H⋯π inter­action is observed.
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spelling pubmed-29777642010-12-30 Methyl N′-[(E)-2-methoxy­benzyl­idene]­hydrazinecarboxyl­ate Lv, Lu-Ping Yu, Wen-Bo Lu, Zhong-Hao Li, Wei-Wei Hu, Xian-Chao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(12)N(2)O(3), crystallizes with two independent mol­ecules in the asymmetric unit. The side chains in the two independent mol­ecules have slightly different orientations, with the C=N—N—C torsion angle being 169.19 (14)° in one of the mol­ecules and −179.86 (14)° in the other. Each independent mol­ecule adopts a trans configuration with respect to the C=N bond. In the crystal structure, mol­ecules are linked into chains running along [001] by N—H⋯O, N—H⋯N and C—H⋯O hydrogen bonds. In addition, an inter­molecular C—H⋯π inter­action is observed. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977764/ /pubmed/21583900 http://dx.doi.org/10.1107/S1600536809014172 Text en © Lv et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Lv, Lu-Ping
Yu, Wen-Bo
Lu, Zhong-Hao
Li, Wei-Wei
Hu, Xian-Chao
Methyl N′-[(E)-2-methoxy­benzyl­idene]­hydrazinecarboxyl­ate
title Methyl N′-[(E)-2-methoxy­benzyl­idene]­hydrazinecarboxyl­ate
title_full Methyl N′-[(E)-2-methoxy­benzyl­idene]­hydrazinecarboxyl­ate
title_fullStr Methyl N′-[(E)-2-methoxy­benzyl­idene]­hydrazinecarboxyl­ate
title_full_unstemmed Methyl N′-[(E)-2-methoxy­benzyl­idene]­hydrazinecarboxyl­ate
title_short Methyl N′-[(E)-2-methoxy­benzyl­idene]­hydrazinecarboxyl­ate
title_sort methyl n′-[(e)-2-methoxy­benzyl­idene]­hydrazinecarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977764/
https://www.ncbi.nlm.nih.gov/pubmed/21583900
http://dx.doi.org/10.1107/S1600536809014172
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AT liweiwei methylne2methoxybenzylidenehydrazinecarboxylate
AT huxianchao methylne2methoxybenzylidenehydrazinecarboxylate

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