(S)-5-Hexyl-1-[(S)-2-hydr­oxy-1-phenyl­ethyl]-4-meth­oxy-1H-pyrrol-2(5H)-one

The title compound, C(19)H(27)NO(3), was obtained by the reaction of (3S,7aR)-7a-hexyl-7-meth­oxy-3-phenyl-2,3-dihydro­pyrrolo[2,1-b]oxazol-5(7aH)-one and triethyl­silane using titanium(IV) chloride as catalyst. In the mol­ecule, the phenyl and dihydro­pyrrolone rings form a dihedral angle of 83.8 (...

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Detalles Bibliográficos
Autores principales: Zheng, Jian-Feng, Jiang, Li-Jiao, Guo, Jian-Nan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977772/
https://www.ncbi.nlm.nih.gov/pubmed/21583908
http://dx.doi.org/10.1107/S1600536809014160
Descripción
Sumario:The title compound, C(19)H(27)NO(3), was obtained by the reaction of (3S,7aR)-7a-hexyl-7-meth­oxy-3-phenyl-2,3-dihydro­pyrrolo[2,1-b]oxazol-5(7aH)-one and triethyl­silane using titanium(IV) chloride as catalyst. In the mol­ecule, the phenyl and dihydro­pyrrolone rings form a dihedral angle of 83.8 (1)°. O—H⋯O hydrogen-bonding inter­actions lead to the formation of a chain parallel to the a axis.

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