(S)-5-Hexyl-1-[(S)-2-hydr­oxy-1-phenyl­ethyl]-4-meth­oxy-1H-pyrrol-2(5H)-one

The title compound, C(19)H(27)NO(3), was obtained by the reaction of (3S,7aR)-7a-hexyl-7-meth­oxy-3-phenyl-2,3-dihydro­pyrrolo[2,1-b]oxazol-5(7aH)-one and triethyl­silane using titanium(IV) chloride as catalyst. In the mol­ecule, the phenyl and dihydro­pyrrolone rings form a dihedral angle of 83.8 (...

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Detalles Bibliográficos
Autores principales: Zheng, Jian-Feng, Jiang, Li-Jiao, Guo, Jian-Nan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977772/
https://www.ncbi.nlm.nih.gov/pubmed/21583908
http://dx.doi.org/10.1107/S1600536809014160
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author Zheng, Jian-Feng
Jiang, Li-Jiao
Guo, Jian-Nan
author_facet Zheng, Jian-Feng
Jiang, Li-Jiao
Guo, Jian-Nan
author_sort Zheng, Jian-Feng
collection PubMed
description The title compound, C(19)H(27)NO(3), was obtained by the reaction of (3S,7aR)-7a-hexyl-7-meth­oxy-3-phenyl-2,3-dihydro­pyrrolo[2,1-b]oxazol-5(7aH)-one and triethyl­silane using titanium(IV) chloride as catalyst. In the mol­ecule, the phenyl and dihydro­pyrrolone rings form a dihedral angle of 83.8 (1)°. O—H⋯O hydrogen-bonding inter­actions lead to the formation of a chain parallel to the a axis.
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spelling pubmed-29777722010-12-30 (S)-5-Hexyl-1-[(S)-2-hydr­oxy-1-phenyl­ethyl]-4-meth­oxy-1H-pyrrol-2(5H)-one Zheng, Jian-Feng Jiang, Li-Jiao Guo, Jian-Nan Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(27)NO(3), was obtained by the reaction of (3S,7aR)-7a-hexyl-7-meth­oxy-3-phenyl-2,3-dihydro­pyrrolo[2,1-b]oxazol-5(7aH)-one and triethyl­silane using titanium(IV) chloride as catalyst. In the mol­ecule, the phenyl and dihydro­pyrrolone rings form a dihedral angle of 83.8 (1)°. O—H⋯O hydrogen-bonding inter­actions lead to the formation of a chain parallel to the a axis. International Union of Crystallography 2009-04-22 /pmc/articles/PMC2977772/ /pubmed/21583908 http://dx.doi.org/10.1107/S1600536809014160 Text en © Zheng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zheng, Jian-Feng
Jiang, Li-Jiao
Guo, Jian-Nan
(S)-5-Hexyl-1-[(S)-2-hydr­oxy-1-phenyl­ethyl]-4-meth­oxy-1H-pyrrol-2(5H)-one
title (S)-5-Hexyl-1-[(S)-2-hydr­oxy-1-phenyl­ethyl]-4-meth­oxy-1H-pyrrol-2(5H)-one
title_full (S)-5-Hexyl-1-[(S)-2-hydr­oxy-1-phenyl­ethyl]-4-meth­oxy-1H-pyrrol-2(5H)-one
title_fullStr (S)-5-Hexyl-1-[(S)-2-hydr­oxy-1-phenyl­ethyl]-4-meth­oxy-1H-pyrrol-2(5H)-one
title_full_unstemmed (S)-5-Hexyl-1-[(S)-2-hydr­oxy-1-phenyl­ethyl]-4-meth­oxy-1H-pyrrol-2(5H)-one
title_short (S)-5-Hexyl-1-[(S)-2-hydr­oxy-1-phenyl­ethyl]-4-meth­oxy-1H-pyrrol-2(5H)-one
title_sort (s)-5-hexyl-1-[(s)-2-hydr­oxy-1-phenyl­ethyl]-4-meth­oxy-1h-pyrrol-2(5h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977772/
https://www.ncbi.nlm.nih.gov/pubmed/21583908
http://dx.doi.org/10.1107/S1600536809014160
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AT guojiannan s5hexyl1s2hydroxy1phenylethyl4methoxy1hpyrrol25hone

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