Cargando…
(Z)-6-[(5-Chloro-2-hydroxyanilino)methylene]-4-methoxycyclohexa-2,4-dienone 0.25-hydrate
The title compound, C(14)H(12)ClNO(3)·0.25H(2)O, exists in the keto–amine form, and the aromatic rings are oriented at a dihedral angle of 7.24 (7)°. Bifurcated intramolecular N—H⋯(O,O) hydrogen bonds result in the formation of planar six- and five-membered rings. In the crystal structure, intermo...
Autores principales: | , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977782/ https://www.ncbi.nlm.nih.gov/pubmed/21583918 http://dx.doi.org/10.1107/S160053680901410X |
Sumario: | The title compound, C(14)H(12)ClNO(3)·0.25H(2)O, exists in the keto–amine form, and the aromatic rings are oriented at a dihedral angle of 7.24 (7)°. Bifurcated intramolecular N—H⋯(O,O) hydrogen bonds result in the formation of planar six- and five-membered rings. In the crystal structure, intermolecular O—H⋯O and C—H⋯O hydrogen bonds link the molecules into chains. π–π contacts between benzene rings [centroid–centroid distance = 3.5065 (9) Å] may further stabilize the structure. There also exists a weak C—H⋯π interaction. |
---|