(Z)-6-[(5-Chloro-2-hydroxy­anilino)­methyl­ene]-4-methoxy­cyclo­hexa-2,4-dienone 0.25-hydrate

The title compound, C(14)H(12)ClNO(3)·0.25H(2)O, exists in the keto–amine form, and the aromatic rings are oriented at a dihedral angle of 7.24 (7)°. Bifurcated intra­molecular N—H⋯(O,O) hydrogen bonds result in the formation of planar six- and five-membered rings. In the crystal structure, inter­mo...

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Autores principales: Özek, Arzu, Büyükgüngör, Orhan, Albayrak, Çiğdem, Odabaşoğlu, Mustafa
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977782/
https://www.ncbi.nlm.nih.gov/pubmed/21583918
http://dx.doi.org/10.1107/S160053680901410X
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author Özek, Arzu
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
author_facet Özek, Arzu
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
author_sort Özek, Arzu
collection PubMed
description The title compound, C(14)H(12)ClNO(3)·0.25H(2)O, exists in the keto–amine form, and the aromatic rings are oriented at a dihedral angle of 7.24 (7)°. Bifurcated intra­molecular N—H⋯(O,O) hydrogen bonds result in the formation of planar six- and five-membered rings. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into chains. π–π contacts between benzene rings [centroid–centroid distance = 3.5065 (9) Å] may further stabilize the structure. There also exists a weak C—H⋯π inter­action.
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spelling pubmed-29777822010-12-30 (Z)-6-[(5-Chloro-2-hydroxy­anilino)­methyl­ene]-4-methoxy­cyclo­hexa-2,4-dienone 0.25-hydrate Özek, Arzu Büyükgüngör, Orhan Albayrak, Çiğdem Odabaşoğlu, Mustafa Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(12)ClNO(3)·0.25H(2)O, exists in the keto–amine form, and the aromatic rings are oriented at a dihedral angle of 7.24 (7)°. Bifurcated intra­molecular N—H⋯(O,O) hydrogen bonds result in the formation of planar six- and five-membered rings. In the crystal structure, inter­molecular O—H⋯O and C—H⋯O hydrogen bonds link the mol­ecules into chains. π–π contacts between benzene rings [centroid–centroid distance = 3.5065 (9) Å] may further stabilize the structure. There also exists a weak C—H⋯π inter­action. International Union of Crystallography 2009-04-25 /pmc/articles/PMC2977782/ /pubmed/21583918 http://dx.doi.org/10.1107/S160053680901410X Text en © Özek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Özek, Arzu
Büyükgüngör, Orhan
Albayrak, Çiğdem
Odabaşoğlu, Mustafa
(Z)-6-[(5-Chloro-2-hydroxy­anilino)­methyl­ene]-4-methoxy­cyclo­hexa-2,4-dienone 0.25-hydrate
title (Z)-6-[(5-Chloro-2-hydroxy­anilino)­methyl­ene]-4-methoxy­cyclo­hexa-2,4-dienone 0.25-hydrate
title_full (Z)-6-[(5-Chloro-2-hydroxy­anilino)­methyl­ene]-4-methoxy­cyclo­hexa-2,4-dienone 0.25-hydrate
title_fullStr (Z)-6-[(5-Chloro-2-hydroxy­anilino)­methyl­ene]-4-methoxy­cyclo­hexa-2,4-dienone 0.25-hydrate
title_full_unstemmed (Z)-6-[(5-Chloro-2-hydroxy­anilino)­methyl­ene]-4-methoxy­cyclo­hexa-2,4-dienone 0.25-hydrate
title_short (Z)-6-[(5-Chloro-2-hydroxy­anilino)­methyl­ene]-4-methoxy­cyclo­hexa-2,4-dienone 0.25-hydrate
title_sort (z)-6-[(5-chloro-2-hydroxy­anilino)­methyl­ene]-4-methoxy­cyclo­hexa-2,4-dienone 0.25-hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977782/
https://www.ncbi.nlm.nih.gov/pubmed/21583918
http://dx.doi.org/10.1107/S160053680901410X
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