2,3,4,6-Tetra-O-acetyl-β-d-galacto­pyranosyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-enecarbo­dithio­ate

The cyclo­hexene ring in the title compound, C(29)H(33)Cl(2)NO(10)S(2), adopts an envelope conformation, with the C atom bearing the two methyl groups representing the flap. This atom deviates by 0.63 (1) Å from the plane through the other five ring atoms (r.m.s. deviation = 0.11 Å). The mol­ecular...

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Detalles Bibliográficos
Autores principales: El Ashry, El Sayed H., Amer, Mohammed R., Shah, M. Raza, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977784/
https://www.ncbi.nlm.nih.gov/pubmed/21583920
http://dx.doi.org/10.1107/S1600536809014743
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author El Ashry, El Sayed H.
Amer, Mohammed R.
Shah, M. Raza
Ng, Seik Weng
author_facet El Ashry, El Sayed H.
Amer, Mohammed R.
Shah, M. Raza
Ng, Seik Weng
author_sort El Ashry, El Sayed H.
collection PubMed
description The cyclo­hexene ring in the title compound, C(29)H(33)Cl(2)NO(10)S(2), adopts an envelope conformation, with the C atom bearing the two methyl groups representing the flap. This atom deviates by 0.63 (1) Å from the plane through the other five ring atoms (r.m.s. deviation = 0.11 Å). The mol­ecular conformation is stabilized by an intra­molecular N—H⋯S hydrogen bond. The crystal studied was a non-merohedral twin, with a minor twin component of 29%.
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spelling pubmed-29777842010-12-30 2,3,4,6-Tetra-O-acetyl-β-d-galacto­pyranosyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-enecarbo­dithio­ate El Ashry, El Sayed H. Amer, Mohammed R. Shah, M. Raza Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Organic Papers The cyclo­hexene ring in the title compound, C(29)H(33)Cl(2)NO(10)S(2), adopts an envelope conformation, with the C atom bearing the two methyl groups representing the flap. This atom deviates by 0.63 (1) Å from the plane through the other five ring atoms (r.m.s. deviation = 0.11 Å). The mol­ecular conformation is stabilized by an intra­molecular N—H⋯S hydrogen bond. The crystal studied was a non-merohedral twin, with a minor twin component of 29%. International Union of Crystallography 2009-04-25 /pmc/articles/PMC2977784/ /pubmed/21583920 http://dx.doi.org/10.1107/S1600536809014743 Text en © El Ashry et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
El Ashry, El Sayed H.
Amer, Mohammed R.
Shah, M. Raza
Ng, Seik Weng
2,3,4,6-Tetra-O-acetyl-β-d-galacto­pyranosyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-enecarbo­dithio­ate
title 2,3,4,6-Tetra-O-acetyl-β-d-galacto­pyranosyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-enecarbo­dithio­ate
title_full 2,3,4,6-Tetra-O-acetyl-β-d-galacto­pyranosyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-enecarbo­dithio­ate
title_fullStr 2,3,4,6-Tetra-O-acetyl-β-d-galacto­pyranosyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-enecarbo­dithio­ate
title_full_unstemmed 2,3,4,6-Tetra-O-acetyl-β-d-galacto­pyranosyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-enecarbo­dithio­ate
title_short 2,3,4,6-Tetra-O-acetyl-β-d-galacto­pyranosyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-enecarbo­dithio­ate
title_sort 2,3,4,6-tetra-o-acetyl-β-d-galacto­pyranosyl 2-(2,4-dichloro­anilino)-4,4-dimethyl-6-oxocyclo­hex-1-enecarbo­dithio­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977784/
https://www.ncbi.nlm.nih.gov/pubmed/21583920
http://dx.doi.org/10.1107/S1600536809014743
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AT shahmraza 2346tetraoacetylbdgalactopyranosyl224dichloroanilino44dimethyl6oxocyclohex1enecarbodithioate
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