(E)-(4-Chloro­benzyl­idene){[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro-1-phenanthryl]­methyl}amine

The title compound, C(27)H(34)ClN, has been synthesized from 4-chloro­benzaldehyde and dehydro­abietylamine. There are two unique mol­ecules in the unit cell. Each mol­ecule has three chiral centres, which exhibit R, S and R absolute configurations. The two cyclo­hexane rings form a trans ring junct...

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Detalles Bibliográficos
Autores principales: Chen, Yu-Xiang, Zhao, Zhen-Dong, Wang, Yu-Min, Bi, Liang-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977794/
https://www.ncbi.nlm.nih.gov/pubmed/21583930
http://dx.doi.org/10.1107/S1600536809013245
Descripción
Sumario:The title compound, C(27)H(34)ClN, has been synthesized from 4-chloro­benzaldehyde and dehydro­abietylamine. There are two unique mol­ecules in the unit cell. Each mol­ecule has three chiral centres, which exhibit R, S and R absolute configurations. The two cyclo­hexane rings form a trans ring junction with classical chair and half-chair conformations.

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