(E)-(4-Chloro­benzyl­idene){[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro-1-phenanthryl]­methyl}amine

The title compound, C(27)H(34)ClN, has been synthesized from 4-chloro­benzaldehyde and dehydro­abietylamine. There are two unique mol­ecules in the unit cell. Each mol­ecule has three chiral centres, which exhibit R, S and R absolute configurations. The two cyclo­hexane rings form a trans ring junct...

Descripción completa

Detalles Bibliográficos
Autores principales: Chen, Yu-Xiang, Zhao, Zhen-Dong, Wang, Yu-Min, Bi, Liang-Wu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977794/
https://www.ncbi.nlm.nih.gov/pubmed/21583930
http://dx.doi.org/10.1107/S1600536809013245
_version_ 1782191190035136512
author Chen, Yu-Xiang
Zhao, Zhen-Dong
Wang, Yu-Min
Bi, Liang-Wu
author_facet Chen, Yu-Xiang
Zhao, Zhen-Dong
Wang, Yu-Min
Bi, Liang-Wu
author_sort Chen, Yu-Xiang
collection PubMed
description The title compound, C(27)H(34)ClN, has been synthesized from 4-chloro­benzaldehyde and dehydro­abietylamine. There are two unique mol­ecules in the unit cell. Each mol­ecule has three chiral centres, which exhibit R, S and R absolute configurations. The two cyclo­hexane rings form a trans ring junction with classical chair and half-chair conformations.
format Text
id pubmed-2977794
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29777942010-12-30 (E)-(4-Chloro­benzyl­idene){[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro-1-phenanthryl]­methyl}amine Chen, Yu-Xiang Zhao, Zhen-Dong Wang, Yu-Min Bi, Liang-Wu Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(27)H(34)ClN, has been synthesized from 4-chloro­benzaldehyde and dehydro­abietylamine. There are two unique mol­ecules in the unit cell. Each mol­ecule has three chiral centres, which exhibit R, S and R absolute configurations. The two cyclo­hexane rings form a trans ring junction with classical chair and half-chair conformations. International Union of Crystallography 2009-04-25 /pmc/articles/PMC2977794/ /pubmed/21583930 http://dx.doi.org/10.1107/S1600536809013245 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Yu-Xiang
Zhao, Zhen-Dong
Wang, Yu-Min
Bi, Liang-Wu
(E)-(4-Chloro­benzyl­idene){[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro-1-phenanthryl]­methyl}amine
title (E)-(4-Chloro­benzyl­idene){[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro-1-phenanthryl]­methyl}amine
title_full (E)-(4-Chloro­benzyl­idene){[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro-1-phenanthryl]­methyl}amine
title_fullStr (E)-(4-Chloro­benzyl­idene){[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro-1-phenanthryl]­methyl}amine
title_full_unstemmed (E)-(4-Chloro­benzyl­idene){[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro-1-phenanthryl]­methyl}amine
title_short (E)-(4-Chloro­benzyl­idene){[(1R,4aS,10aR)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro-1-phenanthryl]­methyl}amine
title_sort (e)-(4-chloro­benzyl­idene){[(1r,4as,10ar)-7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octa­hydro-1-phenanthryl]­methyl}amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977794/
https://www.ncbi.nlm.nih.gov/pubmed/21583930
http://dx.doi.org/10.1107/S1600536809013245
work_keys_str_mv AT chenyuxiang e4chlorobenzylidene1r4as10ar7isopropyl14adimethyl12344a91010aoctahydro1phenanthrylmethylamine
AT zhaozhendong e4chlorobenzylidene1r4as10ar7isopropyl14adimethyl12344a91010aoctahydro1phenanthrylmethylamine
AT wangyumin e4chlorobenzylidene1r4as10ar7isopropyl14adimethyl12344a91010aoctahydro1phenanthrylmethylamine
AT biliangwu e4chlorobenzylidene1r4as10ar7isopropyl14adimethyl12344a91010aoctahydro1phenanthrylmethylamine

Ejemplares similares