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(E)-3-[4-(Dodecyloxy)phenyl]-1-(2-hydroxyphenyl)prop-2-en-1-one
In the title compound, C(27)H(36)O(3), the asymmetric unit consists of two crystallographically independent molecules. The aromatic rings form dihedral angles of 17.1 (2) and 17.6 (2)° in the two molecules. In both molecules, the enone groups adopt an s–cis conformation and the alkoxyl chains are...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977806/ https://www.ncbi.nlm.nih.gov/pubmed/21583943 http://dx.doi.org/10.1107/S1600536809014925 |
Sumario: | In the title compound, C(27)H(36)O(3), the asymmetric unit consists of two crystallographically independent molecules. The aromatic rings form dihedral angles of 17.1 (2) and 17.6 (2)° in the two molecules. In both molecules, the enone groups adopt an s–cis conformation and the alkoxyl chains are in trans conformations curving out of the zigzag plane. Intramolecular O—H⋯O hydrogen bonds involving the keto and hydroxy groups generate S(6) ring motifs. The molecules are stacked alternately in a head-to-tail fashion along the a axis and the crystal structure is stabilized by weak C—H⋯π interactions. The crystal studied was a non-merohedral twin, the ratio of components being 0.788 (2):0.212 (2). |
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