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(E)-3-[4-(Dodec­yloxy)phen­yl]-1-(2-hydroxy­phen­yl)prop-2-en-1-one

In the title compound, C(27)H(36)O(3), the asymmetric unit consists of two crystallographically independent mol­ecules. The aromatic rings form dihedral angles of 17.1 (2) and 17.6 (2)° in the two molecules. In both mol­ecules, the enone groups adopt an s–cis conformation and the alkoxyl chains are...

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Detalles Bibliográficos
Autores principales: Razak, Ibrahim Abdul, Fun, Hoong-Kun, Ngaini, Zainab, Fadzillah, Siti Muhaini Haris, Hussain, Hasnain
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977806/
https://www.ncbi.nlm.nih.gov/pubmed/21583943
http://dx.doi.org/10.1107/S1600536809014925
Descripción
Sumario:In the title compound, C(27)H(36)O(3), the asymmetric unit consists of two crystallographically independent mol­ecules. The aromatic rings form dihedral angles of 17.1 (2) and 17.6 (2)° in the two molecules. In both mol­ecules, the enone groups adopt an s–cis conformation and the alkoxyl chains are in trans conformations curving out of the zigzag plane. Intra­molecular O—H⋯O hydrogen bonds involving the keto and hydr­oxy groups generate S(6) ring motifs. The mol­ecules are stacked alternately in a head-to-tail fashion along the a axis and the crystal structure is stabilized by weak C—H⋯π inter­actions. The crystal studied was a non-merohedral twin, the ratio of components being 0.788 (2):0.212 (2).