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2,4-Diphenyl-4,5-dihydro-3H-pyrido[2,3-b][1,4]diazepine

The asymmetric unit of the title compound, C(20)H(17)N(3), contains two crystallographically independent mol­ecules (A and B). In mol­ecule A, the two benzene rings form dihedral angles of 74.12 (7) and 7.83 (7)° with the pyridine ring, while in mol­ecule B these angles are 77.48 (7) and 21.50 (7)°....

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Yeap, Chin Sing, Hazra, Anita, Jana, Subrata, Goswami, Shyamaprosad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977810/
https://www.ncbi.nlm.nih.gov/pubmed/21583947
http://dx.doi.org/10.1107/S1600536809014901
Descripción
Sumario:The asymmetric unit of the title compound, C(20)H(17)N(3), contains two crystallographically independent mol­ecules (A and B). In mol­ecule A, the two benzene rings form dihedral angles of 74.12 (7) and 7.83 (7)° with the pyridine ring, while in mol­ecule B these angles are 77.48 (7) and 21.50 (7)°. The seven-membered heterocyclic ring adopts a boat conformation in both mol­ecules. In the crystal structure, each of the independent mol­ecules forms a centrosymmetric R (2) (2)(8) dimer linked by paired N—H⋯N hydrogen bonds. The crystal structure is further stabilized by inter­molecular C—H⋯N hydrogen bonds and C—H⋯π inter­actions.