4-[(E)-4-Methoxy­benzyl­ideneamino]-3-{1-[4-(2-methyl­prop­yl)phen­yl]eth­yl}-1H-1,2,4-triazole-5(4H)-thione

In the title compound, C(22)H(26)N(4)OS, the benzene rings of the (2-methyl­prop­yl)phenyl and 4-methoxy­phenyl units form dihedral angles of 66.85 (3) and 25.96 (3)°, respectively, with the triazole ring. The dihedral angle between the two benzene rings is 87.42 (2)°. The –CH(CH(3)) linkage is diso...

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Detalles Bibliográficos
Autores principales: Fun, Hoong-Kun, Jebas, Samuel Robinson, Sujith, K. V, Kalluraya, Balakrishna
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977816/
https://www.ncbi.nlm.nih.gov/pubmed/21583953
http://dx.doi.org/10.1107/S1600536809014949
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author Fun, Hoong-Kun
Jebas, Samuel Robinson
Sujith, K. V
Kalluraya, Balakrishna
author_facet Fun, Hoong-Kun
Jebas, Samuel Robinson
Sujith, K. V
Kalluraya, Balakrishna
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(22)H(26)N(4)OS, the benzene rings of the (2-methyl­prop­yl)phenyl and 4-methoxy­phenyl units form dihedral angles of 66.85 (3) and 25.96 (3)°, respectively, with the triazole ring. The dihedral angle between the two benzene rings is 87.42 (2)°. The –CH(CH(3)) linkage is disordered over two orientations with occupancies of 0.907 (3) and 0.093 (3). An intra­molecular C—H⋯S hydrogen bond generates an S(6) ring motif. Inter­molecular N—H⋯S hydrogen bonds and C—H⋯π inter­actions are observed.
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spelling pubmed-29778162010-12-30 4-[(E)-4-Methoxy­benzyl­ideneamino]-3-{1-[4-(2-methyl­prop­yl)phen­yl]eth­yl}-1H-1,2,4-triazole-5(4H)-thione Fun, Hoong-Kun Jebas, Samuel Robinson Sujith, K. V Kalluraya, Balakrishna Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(22)H(26)N(4)OS, the benzene rings of the (2-methyl­prop­yl)phenyl and 4-methoxy­phenyl units form dihedral angles of 66.85 (3) and 25.96 (3)°, respectively, with the triazole ring. The dihedral angle between the two benzene rings is 87.42 (2)°. The –CH(CH(3)) linkage is disordered over two orientations with occupancies of 0.907 (3) and 0.093 (3). An intra­molecular C—H⋯S hydrogen bond generates an S(6) ring motif. Inter­molecular N—H⋯S hydrogen bonds and C—H⋯π inter­actions are observed. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977816/ /pubmed/21583953 http://dx.doi.org/10.1107/S1600536809014949 Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Jebas, Samuel Robinson
Sujith, K. V
Kalluraya, Balakrishna
4-[(E)-4-Methoxy­benzyl­ideneamino]-3-{1-[4-(2-methyl­prop­yl)phen­yl]eth­yl}-1H-1,2,4-triazole-5(4H)-thione
title 4-[(E)-4-Methoxy­benzyl­ideneamino]-3-{1-[4-(2-methyl­prop­yl)phen­yl]eth­yl}-1H-1,2,4-triazole-5(4H)-thione
title_full 4-[(E)-4-Methoxy­benzyl­ideneamino]-3-{1-[4-(2-methyl­prop­yl)phen­yl]eth­yl}-1H-1,2,4-triazole-5(4H)-thione
title_fullStr 4-[(E)-4-Methoxy­benzyl­ideneamino]-3-{1-[4-(2-methyl­prop­yl)phen­yl]eth­yl}-1H-1,2,4-triazole-5(4H)-thione
title_full_unstemmed 4-[(E)-4-Methoxy­benzyl­ideneamino]-3-{1-[4-(2-methyl­prop­yl)phen­yl]eth­yl}-1H-1,2,4-triazole-5(4H)-thione
title_short 4-[(E)-4-Methoxy­benzyl­ideneamino]-3-{1-[4-(2-methyl­prop­yl)phen­yl]eth­yl}-1H-1,2,4-triazole-5(4H)-thione
title_sort 4-[(e)-4-methoxy­benzyl­ideneamino]-3-{1-[4-(2-methyl­prop­yl)phen­yl]eth­yl}-1h-1,2,4-triazole-5(4h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977816/
https://www.ncbi.nlm.nih.gov/pubmed/21583953
http://dx.doi.org/10.1107/S1600536809014949
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