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7,14-Bis(4-bromophenyl)-2,11,11-trimethyl-1,4,10,12-tetraoxadispiro[4.2.5.2]pentadecane-9,13-dione
In the molecule of the title compound, C(26)H(26)Br(2)O(6), the cyclohexane ring is in a chair conformation, while the five-membered and 1,3-dioxane rings both adopt envelope conformations. The dihedral angle between the benzene rings is 77.21 (3)°. In the crystal structure, weak intermolecular C...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977817/ https://www.ncbi.nlm.nih.gov/pubmed/21583954 http://dx.doi.org/10.1107/S1600536809014251 |
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author | Peng, Ju-hua Ma, Ning Zhang, Ge |
author_facet | Peng, Ju-hua Ma, Ning Zhang, Ge |
author_sort | Peng, Ju-hua |
collection | PubMed |
description | In the molecule of the title compound, C(26)H(26)Br(2)O(6), the cyclohexane ring is in a chair conformation, while the five-membered and 1,3-dioxane rings both adopt envelope conformations. The dihedral angle between the benzene rings is 77.21 (3)°. In the crystal structure, weak intermolecular C—H⋯O interactions link the molecules into centrosymmetric dimers, forming R (2) (2)(14) ring motifs. One of the Br atoms, the methyl C and H atoms, and the C atom bonded to the methyl group of the five-membered ring are disordered over two positions. The Br atoms were refined with occupancies of 0.51 (4) and 0.49 (4), while the C and H atoms were refined with occupancies of 0.320 (18) and 0.680 (18). |
format | Text |
id | pubmed-2977817 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29778172010-12-30 7,14-Bis(4-bromophenyl)-2,11,11-trimethyl-1,4,10,12-tetraoxadispiro[4.2.5.2]pentadecane-9,13-dione Peng, Ju-hua Ma, Ning Zhang, Ge Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(26)H(26)Br(2)O(6), the cyclohexane ring is in a chair conformation, while the five-membered and 1,3-dioxane rings both adopt envelope conformations. The dihedral angle between the benzene rings is 77.21 (3)°. In the crystal structure, weak intermolecular C—H⋯O interactions link the molecules into centrosymmetric dimers, forming R (2) (2)(14) ring motifs. One of the Br atoms, the methyl C and H atoms, and the C atom bonded to the methyl group of the five-membered ring are disordered over two positions. The Br atoms were refined with occupancies of 0.51 (4) and 0.49 (4), while the C and H atoms were refined with occupancies of 0.320 (18) and 0.680 (18). International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977817/ /pubmed/21583954 http://dx.doi.org/10.1107/S1600536809014251 Text en © Peng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Peng, Ju-hua Ma, Ning Zhang, Ge 7,14-Bis(4-bromophenyl)-2,11,11-trimethyl-1,4,10,12-tetraoxadispiro[4.2.5.2]pentadecane-9,13-dione |
title | 7,14-Bis(4-bromophenyl)-2,11,11-trimethyl-1,4,10,12-tetraoxadispiro[4.2.5.2]pentadecane-9,13-dione |
title_full | 7,14-Bis(4-bromophenyl)-2,11,11-trimethyl-1,4,10,12-tetraoxadispiro[4.2.5.2]pentadecane-9,13-dione |
title_fullStr | 7,14-Bis(4-bromophenyl)-2,11,11-trimethyl-1,4,10,12-tetraoxadispiro[4.2.5.2]pentadecane-9,13-dione |
title_full_unstemmed | 7,14-Bis(4-bromophenyl)-2,11,11-trimethyl-1,4,10,12-tetraoxadispiro[4.2.5.2]pentadecane-9,13-dione |
title_short | 7,14-Bis(4-bromophenyl)-2,11,11-trimethyl-1,4,10,12-tetraoxadispiro[4.2.5.2]pentadecane-9,13-dione |
title_sort | 7,14-bis(4-bromophenyl)-2,11,11-trimethyl-1,4,10,12-tetraoxadispiro[4.2.5.2]pentadecane-9,13-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977817/ https://www.ncbi.nlm.nih.gov/pubmed/21583954 http://dx.doi.org/10.1107/S1600536809014251 |
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