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7,14-Bis(4-bromo­phen­yl)-2,11,11-trimethyl-1,4,10,12-tetra­oxa­dispiro­[4.2.5.2]penta­decane-9,13-dione

In the mol­ecule of the title compound, C(26)H(26)Br(2)O(6), the cyclo­hexane ring is in a chair conformation, while the five-membered and 1,3-dioxane rings both adopt envelope conformations. The dihedral angle between the benzene rings is 77.21 (3)°. In the crystal structure, weak inter­molecular C...

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Detalles Bibliográficos
Autores principales: Peng, Ju-hua, Ma, Ning, Zhang, Ge
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977817/
https://www.ncbi.nlm.nih.gov/pubmed/21583954
http://dx.doi.org/10.1107/S1600536809014251
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author Peng, Ju-hua
Ma, Ning
Zhang, Ge
author_facet Peng, Ju-hua
Ma, Ning
Zhang, Ge
author_sort Peng, Ju-hua
collection PubMed
description In the mol­ecule of the title compound, C(26)H(26)Br(2)O(6), the cyclo­hexane ring is in a chair conformation, while the five-membered and 1,3-dioxane rings both adopt envelope conformations. The dihedral angle between the benzene rings is 77.21 (3)°. In the crystal structure, weak inter­molecular C—H⋯O inter­actions link the mol­ecules into centrosymmetric dimers, forming R (2) (2)(14) ring motifs. One of the Br atoms, the methyl C and H atoms, and the C atom bonded to the methyl group of the five-membered ring are disordered over two positions. The Br atoms were refined with occupancies of 0.51 (4) and 0.49 (4), while the C and H atoms were refined with occupancies of 0.320 (18) and 0.680 (18).
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spelling pubmed-29778172010-12-30 7,14-Bis(4-bromo­phen­yl)-2,11,11-trimethyl-1,4,10,12-tetra­oxa­dispiro­[4.2.5.2]penta­decane-9,13-dione Peng, Ju-hua Ma, Ning Zhang, Ge Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(26)H(26)Br(2)O(6), the cyclo­hexane ring is in a chair conformation, while the five-membered and 1,3-dioxane rings both adopt envelope conformations. The dihedral angle between the benzene rings is 77.21 (3)°. In the crystal structure, weak inter­molecular C—H⋯O inter­actions link the mol­ecules into centrosymmetric dimers, forming R (2) (2)(14) ring motifs. One of the Br atoms, the methyl C and H atoms, and the C atom bonded to the methyl group of the five-membered ring are disordered over two positions. The Br atoms were refined with occupancies of 0.51 (4) and 0.49 (4), while the C and H atoms were refined with occupancies of 0.320 (18) and 0.680 (18). International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977817/ /pubmed/21583954 http://dx.doi.org/10.1107/S1600536809014251 Text en © Peng et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Peng, Ju-hua
Ma, Ning
Zhang, Ge
7,14-Bis(4-bromo­phen­yl)-2,11,11-trimethyl-1,4,10,12-tetra­oxa­dispiro­[4.2.5.2]penta­decane-9,13-dione
title 7,14-Bis(4-bromo­phen­yl)-2,11,11-trimethyl-1,4,10,12-tetra­oxa­dispiro­[4.2.5.2]penta­decane-9,13-dione
title_full 7,14-Bis(4-bromo­phen­yl)-2,11,11-trimethyl-1,4,10,12-tetra­oxa­dispiro­[4.2.5.2]penta­decane-9,13-dione
title_fullStr 7,14-Bis(4-bromo­phen­yl)-2,11,11-trimethyl-1,4,10,12-tetra­oxa­dispiro­[4.2.5.2]penta­decane-9,13-dione
title_full_unstemmed 7,14-Bis(4-bromo­phen­yl)-2,11,11-trimethyl-1,4,10,12-tetra­oxa­dispiro­[4.2.5.2]penta­decane-9,13-dione
title_short 7,14-Bis(4-bromo­phen­yl)-2,11,11-trimethyl-1,4,10,12-tetra­oxa­dispiro­[4.2.5.2]penta­decane-9,13-dione
title_sort 7,14-bis(4-bromo­phen­yl)-2,11,11-trimethyl-1,4,10,12-tetra­oxa­dispiro­[4.2.5.2]penta­decane-9,13-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977817/
https://www.ncbi.nlm.nih.gov/pubmed/21583954
http://dx.doi.org/10.1107/S1600536809014251
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