2-Methyl­anilinium dihydrogen phosphate–phospho­ric acid (1/1)

In the title compound, C(7)H(10)N(+)·H(2)PO(4) (−)·H(3)PO(4), there is a clear distinction between the P—O/P=O and P—OH bond lengths. In the crystal, the H(2)PO(4) (−) anions and H(3)PO(4) mol­ecules are linked by O—H⋯O hydrogen bonds, leading to layers propagating in the bc plane. The organic catio...

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Detalles Bibliográficos
Autores principales: Khemiri, Hamed, Akriche, Samah, Rzaigui, Mohamed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977818/
https://www.ncbi.nlm.nih.gov/pubmed/21583955
http://dx.doi.org/10.1107/S1600536809014536
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author Khemiri, Hamed
Akriche, Samah
Rzaigui, Mohamed
author_facet Khemiri, Hamed
Akriche, Samah
Rzaigui, Mohamed
author_sort Khemiri, Hamed
collection PubMed
description In the title compound, C(7)H(10)N(+)·H(2)PO(4) (−)·H(3)PO(4), there is a clear distinction between the P—O/P=O and P—OH bond lengths. In the crystal, the H(2)PO(4) (−) anions and H(3)PO(4) mol­ecules are linked by O—H⋯O hydrogen bonds, leading to layers propagating in the bc plane. The organic cations are located between these layers and inter­act with them by way of N—H⋯O hydrogen bonds.
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spelling pubmed-29778182010-12-30 2-Methyl­anilinium dihydrogen phosphate–phospho­ric acid (1/1) Khemiri, Hamed Akriche, Samah Rzaigui, Mohamed Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(10)N(+)·H(2)PO(4) (−)·H(3)PO(4), there is a clear distinction between the P—O/P=O and P—OH bond lengths. In the crystal, the H(2)PO(4) (−) anions and H(3)PO(4) mol­ecules are linked by O—H⋯O hydrogen bonds, leading to layers propagating in the bc plane. The organic cations are located between these layers and inter­act with them by way of N—H⋯O hydrogen bonds. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977818/ /pubmed/21583955 http://dx.doi.org/10.1107/S1600536809014536 Text en © Khemiri et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khemiri, Hamed
Akriche, Samah
Rzaigui, Mohamed
2-Methyl­anilinium dihydrogen phosphate–phospho­ric acid (1/1)
title 2-Methyl­anilinium dihydrogen phosphate–phospho­ric acid (1/1)
title_full 2-Methyl­anilinium dihydrogen phosphate–phospho­ric acid (1/1)
title_fullStr 2-Methyl­anilinium dihydrogen phosphate–phospho­ric acid (1/1)
title_full_unstemmed 2-Methyl­anilinium dihydrogen phosphate–phospho­ric acid (1/1)
title_short 2-Methyl­anilinium dihydrogen phosphate–phospho­ric acid (1/1)
title_sort 2-methyl­anilinium dihydrogen phosphate–phospho­ric acid (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977818/
https://www.ncbi.nlm.nih.gov/pubmed/21583955
http://dx.doi.org/10.1107/S1600536809014536
work_keys_str_mv AT khemirihamed 2methylaniliniumdihydrogenphosphatephosphoricacid11
AT akrichesamah 2methylaniliniumdihydrogenphosphatephosphoricacid11
AT rzaiguimohamed 2methylaniliniumdihydrogenphosphatephosphoricacid11

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