(E)-N′-(2,5-Dimethoxy­benzyl­idene)-2-(8-quinol­yloxy)acetohydrazide methanol solvate

The two mol­ecules in the asymmetric unit of the title compound, C(20)H(19)N(3)O(4)·CH(4)O, are paired via O—H⋯(O,N), N—H⋯O, and C—H⋯O hydrogen bonds. The mol­ecular skeleton of the acetohydrazide mol­ecule is close to planar; the benzene and quinoline mean planes form a dihedral angle of 3.9 (3)°....

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Detalles Bibliográficos
Autores principales: Wang, Shou-Yu, Yuan, Liang, Xu, Liang, Zhang, Zhen, Diao, Yun-Peng, Lv, De-Cheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977820/
https://www.ncbi.nlm.nih.gov/pubmed/21583957
http://dx.doi.org/10.1107/S1600536809015165
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author Wang, Shou-Yu
Yuan, Liang
Xu, Liang
Zhang, Zhen
Diao, Yun-Peng
Lv, De-Cheng
author_facet Wang, Shou-Yu
Yuan, Liang
Xu, Liang
Zhang, Zhen
Diao, Yun-Peng
Lv, De-Cheng
author_sort Wang, Shou-Yu
collection PubMed
description The two mol­ecules in the asymmetric unit of the title compound, C(20)H(19)N(3)O(4)·CH(4)O, are paired via O—H⋯(O,N), N—H⋯O, and C—H⋯O hydrogen bonds. The mol­ecular skeleton of the acetohydrazide mol­ecule is close to planar; the benzene and quinoline mean planes form a dihedral angle of 3.9 (3)°. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions, indicated by short distances of 3.668 (3) Å, between the centroids of N-containing six-membered rings from neighbouring acetohydrazide mol­ecules.
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spelling pubmed-29778202010-12-30 (E)-N′-(2,5-Dimethoxy­benzyl­idene)-2-(8-quinol­yloxy)acetohydrazide methanol solvate Wang, Shou-Yu Yuan, Liang Xu, Liang Zhang, Zhen Diao, Yun-Peng Lv, De-Cheng Acta Crystallogr Sect E Struct Rep Online Organic Papers The two mol­ecules in the asymmetric unit of the title compound, C(20)H(19)N(3)O(4)·CH(4)O, are paired via O—H⋯(O,N), N—H⋯O, and C—H⋯O hydrogen bonds. The mol­ecular skeleton of the acetohydrazide mol­ecule is close to planar; the benzene and quinoline mean planes form a dihedral angle of 3.9 (3)°. The crystal packing exhibits weak inter­molecular C—H⋯O hydrogen bonds and π–π inter­actions, indicated by short distances of 3.668 (3) Å, between the centroids of N-containing six-membered rings from neighbouring acetohydrazide mol­ecules. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977820/ /pubmed/21583957 http://dx.doi.org/10.1107/S1600536809015165 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wang, Shou-Yu
Yuan, Liang
Xu, Liang
Zhang, Zhen
Diao, Yun-Peng
Lv, De-Cheng
(E)-N′-(2,5-Dimethoxy­benzyl­idene)-2-(8-quinol­yloxy)acetohydrazide methanol solvate
title (E)-N′-(2,5-Dimethoxy­benzyl­idene)-2-(8-quinol­yloxy)acetohydrazide methanol solvate
title_full (E)-N′-(2,5-Dimethoxy­benzyl­idene)-2-(8-quinol­yloxy)acetohydrazide methanol solvate
title_fullStr (E)-N′-(2,5-Dimethoxy­benzyl­idene)-2-(8-quinol­yloxy)acetohydrazide methanol solvate
title_full_unstemmed (E)-N′-(2,5-Dimethoxy­benzyl­idene)-2-(8-quinol­yloxy)acetohydrazide methanol solvate
title_short (E)-N′-(2,5-Dimethoxy­benzyl­idene)-2-(8-quinol­yloxy)acetohydrazide methanol solvate
title_sort (e)-n′-(2,5-dimethoxy­benzyl­idene)-2-(8-quinol­yloxy)acetohydrazide methanol solvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977820/
https://www.ncbi.nlm.nih.gov/pubmed/21583957
http://dx.doi.org/10.1107/S1600536809015165
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