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5,5′-Dimethoxy-2,2′-[(pentane-1,5-diyldioxy)bis(nitrilomethylidyne)]diphenol
The molecule of the title compound, C(21)H(26)N(2)O(6), which lies across a crystallographic inversion centre, crystallizes with two unique half-molecules in the symmetric unit and adopts a linear configuration and the imino group is coplanar with the aromatic ring, making a dihedral angle of 3.26 ...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977826/ https://www.ncbi.nlm.nih.gov/pubmed/21583963 http://dx.doi.org/10.1107/S1600536809014986 |
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author | Sun, Yin-Xia Li, Li Dong, Wen-Kui Wu, Jian-Chao Tong, Jun-Feng |
author_facet | Sun, Yin-Xia Li, Li Dong, Wen-Kui Wu, Jian-Chao Tong, Jun-Feng |
author_sort | Sun, Yin-Xia |
collection | PubMed |
description | The molecule of the title compound, C(21)H(26)N(2)O(6), which lies across a crystallographic inversion centre, crystallizes with two unique half-molecules in the symmetric unit and adopts a linear configuration and the imino group is coplanar with the aromatic ring, making a dihedral angle of 3.26 (3)°. Strong intramolecular O—H⋯N and weak intermolecular O—H⋯O and C—H⋯O hydrogen bonds and weak intermolecular π–π stacking interactions [centroid–centroid distance = 4.419 (2) Å]establish an infinite three-dimensional supramolecular structure. |
format | Text |
id | pubmed-2977826 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29778262010-12-30 5,5′-Dimethoxy-2,2′-[(pentane-1,5-diyldioxy)bis(nitrilomethylidyne)]diphenol Sun, Yin-Xia Li, Li Dong, Wen-Kui Wu, Jian-Chao Tong, Jun-Feng Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(21)H(26)N(2)O(6), which lies across a crystallographic inversion centre, crystallizes with two unique half-molecules in the symmetric unit and adopts a linear configuration and the imino group is coplanar with the aromatic ring, making a dihedral angle of 3.26 (3)°. Strong intramolecular O—H⋯N and weak intermolecular O—H⋯O and C—H⋯O hydrogen bonds and weak intermolecular π–π stacking interactions [centroid–centroid distance = 4.419 (2) Å]establish an infinite three-dimensional supramolecular structure. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977826/ /pubmed/21583963 http://dx.doi.org/10.1107/S1600536809014986 Text en © Sun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sun, Yin-Xia Li, Li Dong, Wen-Kui Wu, Jian-Chao Tong, Jun-Feng 5,5′-Dimethoxy-2,2′-[(pentane-1,5-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title | 5,5′-Dimethoxy-2,2′-[(pentane-1,5-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title_full | 5,5′-Dimethoxy-2,2′-[(pentane-1,5-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title_fullStr | 5,5′-Dimethoxy-2,2′-[(pentane-1,5-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title_full_unstemmed | 5,5′-Dimethoxy-2,2′-[(pentane-1,5-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title_short | 5,5′-Dimethoxy-2,2′-[(pentane-1,5-diyldioxy)bis(nitrilomethylidyne)]diphenol |
title_sort | 5,5′-dimethoxy-2,2′-[(pentane-1,5-diyldioxy)bis(nitrilomethylidyne)]diphenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977826/ https://www.ncbi.nlm.nih.gov/pubmed/21583963 http://dx.doi.org/10.1107/S1600536809014986 |
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