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5,5′-Dimeth­oxy-2,2′-[(pentane-1,5-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol

The mol­ecule of the title compound, C(21)H(26)N(2)O(6), which lies across a crystallographic inversion centre, crystallizes with two unique half-molecules in the symmetric unit and adopts a linear configuration and the imino group is coplanar with the aromatic ring, making a dihedral angle of 3.26 ...

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Detalles Bibliográficos
Autores principales: Sun, Yin-Xia, Li, Li, Dong, Wen-Kui, Wu, Jian-Chao, Tong, Jun-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977826/
https://www.ncbi.nlm.nih.gov/pubmed/21583963
http://dx.doi.org/10.1107/S1600536809014986
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author Sun, Yin-Xia
Li, Li
Dong, Wen-Kui
Wu, Jian-Chao
Tong, Jun-Feng
author_facet Sun, Yin-Xia
Li, Li
Dong, Wen-Kui
Wu, Jian-Chao
Tong, Jun-Feng
author_sort Sun, Yin-Xia
collection PubMed
description The mol­ecule of the title compound, C(21)H(26)N(2)O(6), which lies across a crystallographic inversion centre, crystallizes with two unique half-molecules in the symmetric unit and adopts a linear configuration and the imino group is coplanar with the aromatic ring, making a dihedral angle of 3.26 (3)°. Strong intra­molecular O—H⋯N and weak inter­molecular O—H⋯O and C—H⋯O hydrogen bonds and weak inter­molecular π–π stacking inter­actions [centroid–centroid distance = 4.419 (2) Å]establish an infinite three-dimensional supra­molecular structure.
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spelling pubmed-29778262010-12-30 5,5′-Dimeth­oxy-2,2′-[(pentane-1,5-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol Sun, Yin-Xia Li, Li Dong, Wen-Kui Wu, Jian-Chao Tong, Jun-Feng Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(21)H(26)N(2)O(6), which lies across a crystallographic inversion centre, crystallizes with two unique half-molecules in the symmetric unit and adopts a linear configuration and the imino group is coplanar with the aromatic ring, making a dihedral angle of 3.26 (3)°. Strong intra­molecular O—H⋯N and weak inter­molecular O—H⋯O and C—H⋯O hydrogen bonds and weak inter­molecular π–π stacking inter­actions [centroid–centroid distance = 4.419 (2) Å]establish an infinite three-dimensional supra­molecular structure. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977826/ /pubmed/21583963 http://dx.doi.org/10.1107/S1600536809014986 Text en © Sun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sun, Yin-Xia
Li, Li
Dong, Wen-Kui
Wu, Jian-Chao
Tong, Jun-Feng
5,5′-Dimeth­oxy-2,2′-[(pentane-1,5-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title 5,5′-Dimeth­oxy-2,2′-[(pentane-1,5-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title_full 5,5′-Dimeth­oxy-2,2′-[(pentane-1,5-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title_fullStr 5,5′-Dimeth­oxy-2,2′-[(pentane-1,5-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title_full_unstemmed 5,5′-Dimeth­oxy-2,2′-[(pentane-1,5-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title_short 5,5′-Dimeth­oxy-2,2′-[(pentane-1,5-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
title_sort 5,5′-dimeth­oxy-2,2′-[(pentane-1,5-diyl­dioxy)bis­(nitrilo­methyl­idyne)]diphenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977826/
https://www.ncbi.nlm.nih.gov/pubmed/21583963
http://dx.doi.org/10.1107/S1600536809014986
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