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13-Hydroxy-4,16-dimethyl-4,16-diazapentacyclo[12.3.1.0(1,5).0(5,13).0(7,12)]octadeca-7(12),8,10-triene-6,18-dione
In the title compound, C(18)H(20)N(2)O(3), the N-methylpiperidone ring adopts a chair conformation. The pyrrolidine ring and the five-membered cyclopentane rings adopt envelope conformations. The five-membered ring of the ninhydrin system adopts an envelope conformation with the central C atom dev...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977829/ https://www.ncbi.nlm.nih.gov/pubmed/21583966 http://dx.doi.org/10.1107/S1600536809015293 |
| Sumario: | In the title compound, C(18)H(20)N(2)O(3), the N-methylpiperidone ring adopts a chair conformation. The pyrrolidine ring and the five-membered cyclopentane rings adopt envelope conformations. The five-membered ring of the ninhydrin system adopts an envelope conformation with the central C atom deviating by 0.217 (1)Å from the mean plane through the other atoms. The molecular packing is characterized by intermolecular C—H⋯O and intramolecular C—H⋯O and O—H⋯N interactions. |
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