13-Hydr­oxy-4,16-dimethyl-4,16-diaza­penta­cyclo­[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,18-dione

In the title compound, C(18)H(20)N(2)O(3), the N-methyl­piperidone ring adopts a chair conformation. The pyrrolidine ring and the five-membered cyclo­pentane rings adopt envelope conformations. The five-membered ring of the ninhydrin system adopts an envelope conformation with the central C atom dev...

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Detalles Bibliográficos
Autores principales: Suresh, J., Gurunathan, K., Kumar, R. Suresh, Perumal, S., Lakshman, P. L. Nilantha
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977829/
https://www.ncbi.nlm.nih.gov/pubmed/21583966
http://dx.doi.org/10.1107/S1600536809015293
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author Suresh, J.
Gurunathan, K.
Kumar, R. Suresh
Perumal, S.
Lakshman, P. L. Nilantha
author_facet Suresh, J.
Gurunathan, K.
Kumar, R. Suresh
Perumal, S.
Lakshman, P. L. Nilantha
author_sort Suresh, J.
collection PubMed
description In the title compound, C(18)H(20)N(2)O(3), the N-methyl­piperidone ring adopts a chair conformation. The pyrrolidine ring and the five-membered cyclo­pentane rings adopt envelope conformations. The five-membered ring of the ninhydrin system adopts an envelope conformation with the central C atom deviating by 0.217 (1)Å from the mean plane through the other atoms. The mol­ecular packing is characterized by inter­molecular C—H⋯O and intra­molecular C—H⋯O and O—H⋯N inter­actions.
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spelling pubmed-29778292010-12-30 13-Hydr­oxy-4,16-dimethyl-4,16-diaza­penta­cyclo­[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,18-dione Suresh, J. Gurunathan, K. Kumar, R. Suresh Perumal, S. Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(20)N(2)O(3), the N-methyl­piperidone ring adopts a chair conformation. The pyrrolidine ring and the five-membered cyclo­pentane rings adopt envelope conformations. The five-membered ring of the ninhydrin system adopts an envelope conformation with the central C atom deviating by 0.217 (1)Å from the mean plane through the other atoms. The mol­ecular packing is characterized by inter­molecular C—H⋯O and intra­molecular C—H⋯O and O—H⋯N inter­actions. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977829/ /pubmed/21583966 http://dx.doi.org/10.1107/S1600536809015293 Text en © Suresh et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Suresh, J.
Gurunathan, K.
Kumar, R. Suresh
Perumal, S.
Lakshman, P. L. Nilantha
13-Hydr­oxy-4,16-dimethyl-4,16-diaza­penta­cyclo­[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,18-dione
title 13-Hydr­oxy-4,16-dimethyl-4,16-diaza­penta­cyclo­[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,18-dione
title_full 13-Hydr­oxy-4,16-dimethyl-4,16-diaza­penta­cyclo­[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,18-dione
title_fullStr 13-Hydr­oxy-4,16-dimethyl-4,16-diaza­penta­cyclo­[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,18-dione
title_full_unstemmed 13-Hydr­oxy-4,16-dimethyl-4,16-diaza­penta­cyclo­[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,18-dione
title_short 13-Hydr­oxy-4,16-dimethyl-4,16-diaza­penta­cyclo­[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,18-dione
title_sort 13-hydr­oxy-4,16-dimethyl-4,16-diaza­penta­cyclo­[12.3.1.0(1,5).0(5,13).0(7,12)]octa­deca-7(12),8,10-triene-6,18-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977829/
https://www.ncbi.nlm.nih.gov/pubmed/21583966
http://dx.doi.org/10.1107/S1600536809015293
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