N (1),N (2)-Bis(6-methyl-2-pyrid­yl)formamidine

In the crystal structure of the title mol­ecule, C(13)H(14)N(4), the two pyridyl rings are not coplanar but twisted about the C—N bond with an inter­planar angle of 71.1 (1)°. In the crystal, the mol­ecules form dimers, situated on crystallographic centres of inversion, which are connected via a pai...

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Autores principales: Wu, Chia-Jun, Su, Chang-Wei, Yeh, Chun-Wei, Chen, Jhy-Der, Wang, Ju-Chun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977833/
https://www.ncbi.nlm.nih.gov/pubmed/21583970
http://dx.doi.org/10.1107/S1600536809015591
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author Wu, Chia-Jun
Su, Chang-Wei
Yeh, Chun-Wei
Chen, Jhy-Der
Wang, Ju-Chun
author_facet Wu, Chia-Jun
Su, Chang-Wei
Yeh, Chun-Wei
Chen, Jhy-Der
Wang, Ju-Chun
author_sort Wu, Chia-Jun
collection PubMed
description In the crystal structure of the title mol­ecule, C(13)H(14)N(4), the two pyridyl rings are not coplanar but twisted about the C—N bond with an inter­planar angle of 71.1 (1)°. In the crystal, the mol­ecules form dimers, situated on crystallographic centres of inversion, which are connected via a pair of N—H⋯N hydrogen bonds. C—H⋯π-electron ring inter­actions are also present in the crystal structure. The title mol­ecule adopts an s–cis–anti–s–cis conformation in the solid state.
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spelling pubmed-29778332010-12-30 N (1),N (2)-Bis(6-methyl-2-pyrid­yl)formamidine Wu, Chia-Jun Su, Chang-Wei Yeh, Chun-Wei Chen, Jhy-Der Wang, Ju-Chun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title mol­ecule, C(13)H(14)N(4), the two pyridyl rings are not coplanar but twisted about the C—N bond with an inter­planar angle of 71.1 (1)°. In the crystal, the mol­ecules form dimers, situated on crystallographic centres of inversion, which are connected via a pair of N—H⋯N hydrogen bonds. C—H⋯π-electron ring inter­actions are also present in the crystal structure. The title mol­ecule adopts an s–cis–anti–s–cis conformation in the solid state. International Union of Crystallography 2009-04-30 /pmc/articles/PMC2977833/ /pubmed/21583970 http://dx.doi.org/10.1107/S1600536809015591 Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Wu, Chia-Jun
Su, Chang-Wei
Yeh, Chun-Wei
Chen, Jhy-Der
Wang, Ju-Chun
N (1),N (2)-Bis(6-methyl-2-pyrid­yl)formamidine
title N (1),N (2)-Bis(6-methyl-2-pyrid­yl)formamidine
title_full N (1),N (2)-Bis(6-methyl-2-pyrid­yl)formamidine
title_fullStr N (1),N (2)-Bis(6-methyl-2-pyrid­yl)formamidine
title_full_unstemmed N (1),N (2)-Bis(6-methyl-2-pyrid­yl)formamidine
title_short N (1),N (2)-Bis(6-methyl-2-pyrid­yl)formamidine
title_sort n (1),n (2)-bis(6-methyl-2-pyrid­yl)formamidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2977833/
https://www.ncbi.nlm.nih.gov/pubmed/21583970
http://dx.doi.org/10.1107/S1600536809015591
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