Bis[3-(dihydroxy­boryl)anilinium] sulfate

In the title compound, 2C(6)H(9)BNO(2) (+)·SO(4) (2−), the dihydroxy­boryl group of one of the two independent boronic acid mol­ecules participates in (B)O—H⋯O(B) and N—H⋯O(B) hydrogen bonds, while the second is involved mainly in the formation of the charge-assisted heterodimeric synthon –B(OH)(2)⋯...

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Detalles Bibliográficos
Autores principales: Vega, Araceli, Luna, Rolando, Tlahuext, Hugo, Höpfl, Herbert
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979015/
https://www.ncbi.nlm.nih.gov/pubmed/21579098
http://dx.doi.org/10.1107/S1600536810012092
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author Vega, Araceli
Luna, Rolando
Tlahuext, Hugo
Höpfl, Herbert
author_facet Vega, Araceli
Luna, Rolando
Tlahuext, Hugo
Höpfl, Herbert
author_sort Vega, Araceli
collection PubMed
description In the title compound, 2C(6)H(9)BNO(2) (+)·SO(4) (2−), the dihydroxy­boryl group of one of the two independent boronic acid mol­ecules participates in (B)O—H⋯O(B) and N—H⋯O(B) hydrogen bonds, while the second is involved mainly in the formation of the charge-assisted heterodimeric synthon –B(OH)(2)⋯(−)O(2)SO(2) (−). These aggregates are further connected through N—H⋯O(sulfate) inter­actions, forming a complex three-dimensional hydrogen-bonded network.
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spelling pubmed-29790152010-12-30 Bis[3-(dihydroxy­boryl)anilinium] sulfate Vega, Araceli Luna, Rolando Tlahuext, Hugo Höpfl, Herbert Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, 2C(6)H(9)BNO(2) (+)·SO(4) (2−), the dihydroxy­boryl group of one of the two independent boronic acid mol­ecules participates in (B)O—H⋯O(B) and N—H⋯O(B) hydrogen bonds, while the second is involved mainly in the formation of the charge-assisted heterodimeric synthon –B(OH)(2)⋯(−)O(2)SO(2) (−). These aggregates are further connected through N—H⋯O(sulfate) inter­actions, forming a complex three-dimensional hydrogen-bonded network. International Union of Crystallography 2010-04-10 /pmc/articles/PMC2979015/ /pubmed/21579098 http://dx.doi.org/10.1107/S1600536810012092 Text en © Vega et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vega, Araceli
Luna, Rolando
Tlahuext, Hugo
Höpfl, Herbert
Bis[3-(dihydroxy­boryl)anilinium] sulfate
title Bis[3-(dihydroxy­boryl)anilinium] sulfate
title_full Bis[3-(dihydroxy­boryl)anilinium] sulfate
title_fullStr Bis[3-(dihydroxy­boryl)anilinium] sulfate
title_full_unstemmed Bis[3-(dihydroxy­boryl)anilinium] sulfate
title_short Bis[3-(dihydroxy­boryl)anilinium] sulfate
title_sort bis[3-(dihydroxy­boryl)anilinium] sulfate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979015/
https://www.ncbi.nlm.nih.gov/pubmed/21579098
http://dx.doi.org/10.1107/S1600536810012092
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AT lunarolando bis3dihydroxyborylaniliniumsulfate
AT tlahuexthugo bis3dihydroxyborylaniliniumsulfate
AT hopflherbert bis3dihydroxyborylaniliniumsulfate

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