Cargando…

2-(4-Methoxy­phen­yl)-6-trifluoro­methyl-1H-pyrrolo[3,2-c]quinoline monohydrate

In the title compound, C(19)H(13)F(3)N(2)O·H(2)O, the phenyl and pyrroloquinoline ring system are close to coplanar [dihedral angle = 10.94 (4)°]. The meth­oxy group also is almost coplanar with the phenyl ring [5.4 (1)°]. In the crystal structure N—H⋯O(water) and water–quinoline O—H⋯N hydrogen bond...

Descripción completa

Detalles Bibliográficos
Autores principales: Dutkiewicz, Grzegorz, Mayekar, Anil N., Yathirajan, H. S., Narayana, B., Kubicki, Maciej
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979020/
https://www.ncbi.nlm.nih.gov/pubmed/21579163
http://dx.doi.org/10.1107/S1600536810013644
_version_ 1782191324180512768
author Dutkiewicz, Grzegorz
Mayekar, Anil N.
Yathirajan, H. S.
Narayana, B.
Kubicki, Maciej
author_facet Dutkiewicz, Grzegorz
Mayekar, Anil N.
Yathirajan, H. S.
Narayana, B.
Kubicki, Maciej
author_sort Dutkiewicz, Grzegorz
collection PubMed
description In the title compound, C(19)H(13)F(3)N(2)O·H(2)O, the phenyl and pyrroloquinoline ring system are close to coplanar [dihedral angle = 10.94 (4)°]. The meth­oxy group also is almost coplanar with the phenyl ring [5.4 (1)°]. In the crystal structure N—H⋯O(water) and water–quinoline O—H⋯N hydrogen bonds build up a supra­molecular chain-like arrangement along [001]. The remaining H atom of the water mol­ecule does not take part in classical hydrogen bonds. Instead, this O—H bond points toward the center of the phenyl ring of a neighbouring mol­ecule. Weak C—H⋯O and C—H⋯π inter­actions are also present.
format Text
id pubmed-2979020
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29790202010-12-30 2-(4-Methoxy­phen­yl)-6-trifluoro­methyl-1H-pyrrolo[3,2-c]quinoline monohydrate Dutkiewicz, Grzegorz Mayekar, Anil N. Yathirajan, H. S. Narayana, B. Kubicki, Maciej Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(19)H(13)F(3)N(2)O·H(2)O, the phenyl and pyrroloquinoline ring system are close to coplanar [dihedral angle = 10.94 (4)°]. The meth­oxy group also is almost coplanar with the phenyl ring [5.4 (1)°]. In the crystal structure N—H⋯O(water) and water–quinoline O—H⋯N hydrogen bonds build up a supra­molecular chain-like arrangement along [001]. The remaining H atom of the water mol­ecule does not take part in classical hydrogen bonds. Instead, this O—H bond points toward the center of the phenyl ring of a neighbouring mol­ecule. Weak C—H⋯O and C—H⋯π inter­actions are also present. International Union of Crystallography 2010-04-17 /pmc/articles/PMC2979020/ /pubmed/21579163 http://dx.doi.org/10.1107/S1600536810013644 Text en © Dutkiewicz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dutkiewicz, Grzegorz
Mayekar, Anil N.
Yathirajan, H. S.
Narayana, B.
Kubicki, Maciej
2-(4-Methoxy­phen­yl)-6-trifluoro­methyl-1H-pyrrolo[3,2-c]quinoline monohydrate
title 2-(4-Methoxy­phen­yl)-6-trifluoro­methyl-1H-pyrrolo[3,2-c]quinoline monohydrate
title_full 2-(4-Methoxy­phen­yl)-6-trifluoro­methyl-1H-pyrrolo[3,2-c]quinoline monohydrate
title_fullStr 2-(4-Methoxy­phen­yl)-6-trifluoro­methyl-1H-pyrrolo[3,2-c]quinoline monohydrate
title_full_unstemmed 2-(4-Methoxy­phen­yl)-6-trifluoro­methyl-1H-pyrrolo[3,2-c]quinoline monohydrate
title_short 2-(4-Methoxy­phen­yl)-6-trifluoro­methyl-1H-pyrrolo[3,2-c]quinoline monohydrate
title_sort 2-(4-methoxy­phen­yl)-6-trifluoro­methyl-1h-pyrrolo[3,2-c]quinoline monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979020/
https://www.ncbi.nlm.nih.gov/pubmed/21579163
http://dx.doi.org/10.1107/S1600536810013644
work_keys_str_mv AT dutkiewiczgrzegorz 24methoxyphenyl6trifluoromethyl1hpyrrolo32cquinolinemonohydrate
AT mayekaraniln 24methoxyphenyl6trifluoromethyl1hpyrrolo32cquinolinemonohydrate
AT yathirajanhs 24methoxyphenyl6trifluoromethyl1hpyrrolo32cquinolinemonohydrate
AT narayanab 24methoxyphenyl6trifluoromethyl1hpyrrolo32cquinolinemonohydrate
AT kubickimaciej 24methoxyphenyl6trifluoromethyl1hpyrrolo32cquinolinemonohydrate