trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]dipyridine­cobalt(II) hemihydrate

The asymmeric unit of the title compound, [Co(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa­hedral trans-[Co(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol­ecule and a half-mol­ecule of water, which lies on a twofold rotation axis. A thre...

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Autores principales: Wang, Yan-Fei, Zou, Hong-Li, Luo, Xu-Jian, Chen, Zhen-Feng, Liang, Hong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979022/
https://www.ncbi.nlm.nih.gov/pubmed/21579035
http://dx.doi.org/10.1107/S1600536810013802
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author Wang, Yan-Fei
Zou, Hong-Li
Luo, Xu-Jian
Chen, Zhen-Feng
Liang, Hong
author_facet Wang, Yan-Fei
Zou, Hong-Li
Luo, Xu-Jian
Chen, Zhen-Feng
Liang, Hong
author_sort Wang, Yan-Fei
collection PubMed
description The asymmeric unit of the title compound, [Co(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa­hedral trans-[Co(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol­ecule and a half-mol­ecule of water, which lies on a twofold rotation axis. A three-dimensional network is generated by N—H⋯O and O—H⋯O hydrogen bonds between the complex and the water mol­ecules.
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spelling pubmed-29790222010-12-30 trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]dipyridine­cobalt(II) hemihydrate Wang, Yan-Fei Zou, Hong-Li Luo, Xu-Jian Chen, Zhen-Feng Liang, Hong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmeric unit of the title compound, [Co(C(10)H(9)N(4)O(2)S)(2)(C(5)H(5)N)(2)]·0.5H(2)O, contains the distorted octa­hedral trans-[Co(sdz)(2)(py)(2)] (sdz is the sulfadiazine anion and py is pyridine) complex mol­ecule and a half-mol­ecule of water, which lies on a twofold rotation axis. A three-dimensional network is generated by N—H⋯O and O—H⋯O hydrogen bonds between the complex and the water mol­ecules. International Union of Crystallography 2010-04-21 /pmc/articles/PMC2979022/ /pubmed/21579035 http://dx.doi.org/10.1107/S1600536810013802 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yan-Fei
Zou, Hong-Li
Luo, Xu-Jian
Chen, Zhen-Feng
Liang, Hong
trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]dipyridine­cobalt(II) hemihydrate
title trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]dipyridine­cobalt(II) hemihydrate
title_full trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]dipyridine­cobalt(II) hemihydrate
title_fullStr trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]dipyridine­cobalt(II) hemihydrate
title_full_unstemmed trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]dipyridine­cobalt(II) hemihydrate
title_short trans-Bis[4-amino-N-(pyrimidin-2-yl)benzene­sulfonamidato]dipyridine­cobalt(II) hemihydrate
title_sort trans-bis[4-amino-n-(pyrimidin-2-yl)benzene­sulfonamidato]dipyridine­cobalt(ii) hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979022/
https://www.ncbi.nlm.nih.gov/pubmed/21579035
http://dx.doi.org/10.1107/S1600536810013802
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