Redetermination of di-μ-hydrido-hexa­hydridotetra­kis(tetra­hydro­furan)dialuminium(III)magnesium(II)

The structure of the title compound, [Mg(AlH(4))(2)(C(4)H(8)O)(4)], has been redetermined at 150 K. The Mg(II) ion is hexa­coordinated to four tetra­hydro­furan (THF) ligands, and two AlH(4) (−) anions through bridging H atoms. The Al—H distances are more precise compared to those previously determi...

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Autores principales: Lingam, Hima Kumar, Chen, Xuenian, Yisgedu, Teshome, Huang, Zhenguo, Zhao, Ji-Cheng, Shore, Sheldon G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979026/
https://www.ncbi.nlm.nih.gov/pubmed/21579056
http://dx.doi.org/10.1107/S1600536810014200
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author Lingam, Hima Kumar
Chen, Xuenian
Yisgedu, Teshome
Huang, Zhenguo
Zhao, Ji-Cheng
Shore, Sheldon G.
author_facet Lingam, Hima Kumar
Chen, Xuenian
Yisgedu, Teshome
Huang, Zhenguo
Zhao, Ji-Cheng
Shore, Sheldon G.
author_sort Lingam, Hima Kumar
collection PubMed
description The structure of the title compound, [Mg(AlH(4))(2)(C(4)H(8)O)(4)], has been redetermined at 150 K. The Mg(II) ion is hexa­coordinated to four tetra­hydro­furan (THF) ligands, and two AlH(4) (−) anions through bridging H atoms. The Al—H distances are more precise compared to those previously determined [Nöth et al. (1995 ▶). Chem. Ber. 128, 999–1006; Fichtner & Fuhr (2002 ▶). J. Alloys Compd, 345, 386–396]. The mol­ecule has twofold rotation symmetry.
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spelling pubmed-29790262010-12-30 Redetermination of di-μ-hydrido-hexa­hydridotetra­kis(tetra­hydro­furan)dialuminium(III)magnesium(II) Lingam, Hima Kumar Chen, Xuenian Yisgedu, Teshome Huang, Zhenguo Zhao, Ji-Cheng Shore, Sheldon G. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Mg(AlH(4))(2)(C(4)H(8)O)(4)], has been redetermined at 150 K. The Mg(II) ion is hexa­coordinated to four tetra­hydro­furan (THF) ligands, and two AlH(4) (−) anions through bridging H atoms. The Al—H distances are more precise compared to those previously determined [Nöth et al. (1995 ▶). Chem. Ber. 128, 999–1006; Fichtner & Fuhr (2002 ▶). J. Alloys Compd, 345, 386–396]. The mol­ecule has twofold rotation symmetry. International Union of Crystallography 2010-04-28 /pmc/articles/PMC2979026/ /pubmed/21579056 http://dx.doi.org/10.1107/S1600536810014200 Text en © Lingam et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lingam, Hima Kumar
Chen, Xuenian
Yisgedu, Teshome
Huang, Zhenguo
Zhao, Ji-Cheng
Shore, Sheldon G.
Redetermination of di-μ-hydrido-hexa­hydridotetra­kis(tetra­hydro­furan)dialuminium(III)magnesium(II)
title Redetermination of di-μ-hydrido-hexa­hydridotetra­kis(tetra­hydro­furan)dialuminium(III)magnesium(II)
title_full Redetermination of di-μ-hydrido-hexa­hydridotetra­kis(tetra­hydro­furan)dialuminium(III)magnesium(II)
title_fullStr Redetermination of di-μ-hydrido-hexa­hydridotetra­kis(tetra­hydro­furan)dialuminium(III)magnesium(II)
title_full_unstemmed Redetermination of di-μ-hydrido-hexa­hydridotetra­kis(tetra­hydro­furan)dialuminium(III)magnesium(II)
title_short Redetermination of di-μ-hydrido-hexa­hydridotetra­kis(tetra­hydro­furan)dialuminium(III)magnesium(II)
title_sort redetermination of di-μ-hydrido-hexa­hydridotetra­kis(tetra­hydro­furan)dialuminium(iii)magnesium(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979026/
https://www.ncbi.nlm.nih.gov/pubmed/21579056
http://dx.doi.org/10.1107/S1600536810014200
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