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(Benzoato-κO)bis(1,10-phenanthroline-κ(2) N,N′)copper(II) chloride benzoic acid disolvate
In the title complex, [Cu(C(7)H(5)O(2))(C(12)H(8)N(2))(2)]Cl·2C(6)H(5)COOH, the Cu(II) ion is coordinated by one carboxylate O atom from a benzoate anion and four N atoms from two phenantroline ligands in a distorted five-coordinate trigonal-bipyramidal CuON(4) chromophore. The Cu(2+) and the Cl(−...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979027/ https://www.ncbi.nlm.nih.gov/pubmed/21578993 http://dx.doi.org/10.1107/S1600536810011487 |
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author | Huang, Wen-Xiang Liu, Bin-Bin Lin, Jian-Li |
author_facet | Huang, Wen-Xiang Liu, Bin-Bin Lin, Jian-Li |
author_sort | Huang, Wen-Xiang |
collection | PubMed |
description | In the title complex, [Cu(C(7)H(5)O(2))(C(12)H(8)N(2))(2)]Cl·2C(6)H(5)COOH, the Cu(II) ion is coordinated by one carboxylate O atom from a benzoate anion and four N atoms from two phenantroline ligands in a distorted five-coordinate trigonal-bipyramidal CuON(4) chromophore. The Cu(2+) and the Cl(−) ion are imposed by a twofold rotation axiss which also bisects the equally disordered benzoate anion. In the crystal, the molecules are assembled into chains along [010] by C—H⋯Cl, O—H⋯Cl and C—H⋯O hydrogen-bonding interactions. The resulting chains are further connected into two-dimensional supramolecular layers parallel to [100] by interchain π⋯π stacking interactions [centroid–centroid distance = 3.823 (5) Å] between the phenanthroline ligands and the benzoic acid molecules, and by C—H⋯O hydrogen-bonding interactions. Strong π⋯π stacking interactions between adjacent phenantroline ligands [3.548 (4) Å] assemble the layers into a three-dimensional supramolecular architecture. |
format | Text |
id | pubmed-2979027 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29790272010-12-30 (Benzoato-κO)bis(1,10-phenanthroline-κ(2) N,N′)copper(II) chloride benzoic acid disolvate Huang, Wen-Xiang Liu, Bin-Bin Lin, Jian-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(7)H(5)O(2))(C(12)H(8)N(2))(2)]Cl·2C(6)H(5)COOH, the Cu(II) ion is coordinated by one carboxylate O atom from a benzoate anion and four N atoms from two phenantroline ligands in a distorted five-coordinate trigonal-bipyramidal CuON(4) chromophore. The Cu(2+) and the Cl(−) ion are imposed by a twofold rotation axiss which also bisects the equally disordered benzoate anion. In the crystal, the molecules are assembled into chains along [010] by C—H⋯Cl, O—H⋯Cl and C—H⋯O hydrogen-bonding interactions. The resulting chains are further connected into two-dimensional supramolecular layers parallel to [100] by interchain π⋯π stacking interactions [centroid–centroid distance = 3.823 (5) Å] between the phenanthroline ligands and the benzoic acid molecules, and by C—H⋯O hydrogen-bonding interactions. Strong π⋯π stacking interactions between adjacent phenantroline ligands [3.548 (4) Å] assemble the layers into a three-dimensional supramolecular architecture. International Union of Crystallography 2010-04-02 /pmc/articles/PMC2979027/ /pubmed/21578993 http://dx.doi.org/10.1107/S1600536810011487 Text en © Huang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Huang, Wen-Xiang Liu, Bin-Bin Lin, Jian-Li (Benzoato-κO)bis(1,10-phenanthroline-κ(2) N,N′)copper(II) chloride benzoic acid disolvate |
title | (Benzoato-κO)bis(1,10-phenanthroline-κ(2)
N,N′)copper(II) chloride benzoic acid disolvate |
title_full | (Benzoato-κO)bis(1,10-phenanthroline-κ(2)
N,N′)copper(II) chloride benzoic acid disolvate |
title_fullStr | (Benzoato-κO)bis(1,10-phenanthroline-κ(2)
N,N′)copper(II) chloride benzoic acid disolvate |
title_full_unstemmed | (Benzoato-κO)bis(1,10-phenanthroline-κ(2)
N,N′)copper(II) chloride benzoic acid disolvate |
title_short | (Benzoato-κO)bis(1,10-phenanthroline-κ(2)
N,N′)copper(II) chloride benzoic acid disolvate |
title_sort | (benzoato-κo)bis(1,10-phenanthroline-κ(2)
n,n′)copper(ii) chloride benzoic acid disolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979027/ https://www.ncbi.nlm.nih.gov/pubmed/21578993 http://dx.doi.org/10.1107/S1600536810011487 |
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