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(Benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) chloride benzoic acid disolvate

In the title complex, [Cu(C(7)H(5)O(2))(C(12)H(8)N(2))(2)]Cl·2C(6)H(5)CO­OH, the Cu(II) ion is coordinated by one carboxyl­ate O atom from a benzoate anion and four N atoms from two phenantroline ligands in a distorted five-coordinate trigonal-bipyramidal CuON(4) chromophore. The Cu(2+) and the Cl(−...

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Autores principales: Huang, Wen-Xiang, Liu, Bin-Bin, Lin, Jian-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979027/
https://www.ncbi.nlm.nih.gov/pubmed/21578993
http://dx.doi.org/10.1107/S1600536810011487
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author Huang, Wen-Xiang
Liu, Bin-Bin
Lin, Jian-Li
author_facet Huang, Wen-Xiang
Liu, Bin-Bin
Lin, Jian-Li
author_sort Huang, Wen-Xiang
collection PubMed
description In the title complex, [Cu(C(7)H(5)O(2))(C(12)H(8)N(2))(2)]Cl·2C(6)H(5)CO­OH, the Cu(II) ion is coordinated by one carboxyl­ate O atom from a benzoate anion and four N atoms from two phenantroline ligands in a distorted five-coordinate trigonal-bipyramidal CuON(4) chromophore. The Cu(2+) and the Cl(−) ion are imposed by a twofold rotation axiss which also bisects the equally disordered benzoate anion. In the crystal, the mol­ecules are assembled into chains along [010] by C—H⋯Cl, O—H⋯Cl and C—H⋯O hydrogen-bonding inter­actions. The resulting chains are further connected into two-dimensional supra­molecular layers parallel to [100] by inter­chain π⋯π stacking inter­actions [centroid–centroid distance = 3.823 (5) Å] between the phenanthroline ligands and the benzoic acid mol­ecules, and by C—H⋯O hydrogen-bonding inter­actions. Strong π⋯π stacking inter­actions between adjacent phenantroline ligands [3.548 (4) Å] assemble the layers into a three-dimensional supra­molecular architecture.
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spelling pubmed-29790272010-12-30 (Benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) chloride benzoic acid disolvate Huang, Wen-Xiang Liu, Bin-Bin Lin, Jian-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(7)H(5)O(2))(C(12)H(8)N(2))(2)]Cl·2C(6)H(5)CO­OH, the Cu(II) ion is coordinated by one carboxyl­ate O atom from a benzoate anion and four N atoms from two phenantroline ligands in a distorted five-coordinate trigonal-bipyramidal CuON(4) chromophore. The Cu(2+) and the Cl(−) ion are imposed by a twofold rotation axiss which also bisects the equally disordered benzoate anion. In the crystal, the mol­ecules are assembled into chains along [010] by C—H⋯Cl, O—H⋯Cl and C—H⋯O hydrogen-bonding inter­actions. The resulting chains are further connected into two-dimensional supra­molecular layers parallel to [100] by inter­chain π⋯π stacking inter­actions [centroid–centroid distance = 3.823 (5) Å] between the phenanthroline ligands and the benzoic acid mol­ecules, and by C—H⋯O hydrogen-bonding inter­actions. Strong π⋯π stacking inter­actions between adjacent phenantroline ligands [3.548 (4) Å] assemble the layers into a three-dimensional supra­molecular architecture. International Union of Crystallography 2010-04-02 /pmc/articles/PMC2979027/ /pubmed/21578993 http://dx.doi.org/10.1107/S1600536810011487 Text en © Huang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Wen-Xiang
Liu, Bin-Bin
Lin, Jian-Li
(Benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) chloride benzoic acid disolvate
title (Benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) chloride benzoic acid disolvate
title_full (Benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) chloride benzoic acid disolvate
title_fullStr (Benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) chloride benzoic acid disolvate
title_full_unstemmed (Benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) chloride benzoic acid disolvate
title_short (Benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)copper(II) chloride benzoic acid disolvate
title_sort (benzoato-κo)bis­(1,10-phenanthroline-κ(2) n,n′)copper(ii) chloride benzoic acid disolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979027/
https://www.ncbi.nlm.nih.gov/pubmed/21578993
http://dx.doi.org/10.1107/S1600536810011487
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