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Bis(1,3-benzothia­zole-2-thiol­ato)[(Z)-methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-(methoxy­imino)acetate]nickel(II)

In the title compound, [Ni(C(7)H(4)NS(2))(2)(C(7)H(9)N(3)O(3)S)], the Ni(II) ion is in a slightly distorted N(4)S(2) octa­hedral coordination environment. The two benzothia­zole-2-thiol­ate ligands chelate via their thia­zole N and thiol­ate S atoms while the methyl 2-(2-amino­thia­zol-4-yl)-2-(meth...

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Detalles Bibliográficos
Autores principales: Khan, Islam Ullah, Şahin, Onur, Jillani, Shehzada Muhammad Sajid, Sharif, Shahzad, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979032/
https://www.ncbi.nlm.nih.gov/pubmed/21579063
http://dx.doi.org/10.1107/S1600536810015072
Descripción
Sumario:In the title compound, [Ni(C(7)H(4)NS(2))(2)(C(7)H(9)N(3)O(3)S)], the Ni(II) ion is in a slightly distorted N(4)S(2) octa­hedral coordination environment. The two benzothia­zole-2-thiol­ate ligands chelate via their thia­zole N and thiol­ate S atoms while the methyl 2-(2-amino­thia­zol-4-yl)-2-(methoxy­imino)acetate also acts as a chelate ligand binding through the thia­zole and imino N atoms. Intra­molecular N—H⋯N, C—H⋯N and C—H⋯O inter­actions contribute to the mol­ecular conformation. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds produce R (1) (2)(6) rings and generate chains along the c axis. An extensive one-dimensional supra­molecular network of N—H⋯O hydrogen bonds and C—H⋯π inter­actions is responsible for the crystal structure stabilization.