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Bis(1,3-benzothia­zole-2-thiol­ato)[(Z)-methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-(methoxy­imino)acetate]nickel(II)

In the title compound, [Ni(C(7)H(4)NS(2))(2)(C(7)H(9)N(3)O(3)S)], the Ni(II) ion is in a slightly distorted N(4)S(2) octa­hedral coordination environment. The two benzothia­zole-2-thiol­ate ligands chelate via their thia­zole N and thiol­ate S atoms while the methyl 2-(2-amino­thia­zol-4-yl)-2-(meth...

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Autores principales: Khan, Islam Ullah, Şahin, Onur, Jillani, Shehzada Muhammad Sajid, Sharif, Shahzad, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979032/
https://www.ncbi.nlm.nih.gov/pubmed/21579063
http://dx.doi.org/10.1107/S1600536810015072
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author Khan, Islam Ullah
Şahin, Onur
Jillani, Shehzada Muhammad Sajid
Sharif, Shahzad
Büyükgüngör, Orhan
author_facet Khan, Islam Ullah
Şahin, Onur
Jillani, Shehzada Muhammad Sajid
Sharif, Shahzad
Büyükgüngör, Orhan
author_sort Khan, Islam Ullah
collection PubMed
description In the title compound, [Ni(C(7)H(4)NS(2))(2)(C(7)H(9)N(3)O(3)S)], the Ni(II) ion is in a slightly distorted N(4)S(2) octa­hedral coordination environment. The two benzothia­zole-2-thiol­ate ligands chelate via their thia­zole N and thiol­ate S atoms while the methyl 2-(2-amino­thia­zol-4-yl)-2-(methoxy­imino)acetate also acts as a chelate ligand binding through the thia­zole and imino N atoms. Intra­molecular N—H⋯N, C—H⋯N and C—H⋯O inter­actions contribute to the mol­ecular conformation. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds produce R (1) (2)(6) rings and generate chains along the c axis. An extensive one-dimensional supra­molecular network of N—H⋯O hydrogen bonds and C—H⋯π inter­actions is responsible for the crystal structure stabilization.
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spelling pubmed-29790322010-12-30 Bis(1,3-benzothia­zole-2-thiol­ato)[(Z)-methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-(methoxy­imino)acetate]nickel(II) Khan, Islam Ullah Şahin, Onur Jillani, Shehzada Muhammad Sajid Sharif, Shahzad Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(7)H(4)NS(2))(2)(C(7)H(9)N(3)O(3)S)], the Ni(II) ion is in a slightly distorted N(4)S(2) octa­hedral coordination environment. The two benzothia­zole-2-thiol­ate ligands chelate via their thia­zole N and thiol­ate S atoms while the methyl 2-(2-amino­thia­zol-4-yl)-2-(methoxy­imino)acetate also acts as a chelate ligand binding through the thia­zole and imino N atoms. Intra­molecular N—H⋯N, C—H⋯N and C—H⋯O inter­actions contribute to the mol­ecular conformation. In the crystal structure, inter­molecular N—H⋯O hydrogen bonds produce R (1) (2)(6) rings and generate chains along the c axis. An extensive one-dimensional supra­molecular network of N—H⋯O hydrogen bonds and C—H⋯π inter­actions is responsible for the crystal structure stabilization. International Union of Crystallography 2010-04-30 /pmc/articles/PMC2979032/ /pubmed/21579063 http://dx.doi.org/10.1107/S1600536810015072 Text en © Khan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khan, Islam Ullah
Şahin, Onur
Jillani, Shehzada Muhammad Sajid
Sharif, Shahzad
Büyükgüngör, Orhan
Bis(1,3-benzothia­zole-2-thiol­ato)[(Z)-methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-(methoxy­imino)acetate]nickel(II)
title Bis(1,3-benzothia­zole-2-thiol­ato)[(Z)-methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-(methoxy­imino)acetate]nickel(II)
title_full Bis(1,3-benzothia­zole-2-thiol­ato)[(Z)-methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-(methoxy­imino)acetate]nickel(II)
title_fullStr Bis(1,3-benzothia­zole-2-thiol­ato)[(Z)-methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-(methoxy­imino)acetate]nickel(II)
title_full_unstemmed Bis(1,3-benzothia­zole-2-thiol­ato)[(Z)-methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-(methoxy­imino)acetate]nickel(II)
title_short Bis(1,3-benzothia­zole-2-thiol­ato)[(Z)-methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-(methoxy­imino)acetate]nickel(II)
title_sort bis(1,3-benzothia­zole-2-thiol­ato)[(z)-methyl 2-(2-amino-1,3-thia­zol-4-yl)-2-(methoxy­imino)acetate]nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979032/
https://www.ncbi.nlm.nih.gov/pubmed/21579063
http://dx.doi.org/10.1107/S1600536810015072
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