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Bis(1,3-benzothiazole-2-thiolato)[(Z)-methyl 2-(2-amino-1,3-thiazol-4-yl)-2-(methoxyimino)acetate]nickel(II)
In the title compound, [Ni(C(7)H(4)NS(2))(2)(C(7)H(9)N(3)O(3)S)], the Ni(II) ion is in a slightly distorted N(4)S(2) octahedral coordination environment. The two benzothiazole-2-thiolate ligands chelate via their thiazole N and thiolate S atoms while the methyl 2-(2-aminothiazol-4-yl)-2-(meth...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979032/ https://www.ncbi.nlm.nih.gov/pubmed/21579063 http://dx.doi.org/10.1107/S1600536810015072 |
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author | Khan, Islam Ullah Şahin, Onur Jillani, Shehzada Muhammad Sajid Sharif, Shahzad Büyükgüngör, Orhan |
author_facet | Khan, Islam Ullah Şahin, Onur Jillani, Shehzada Muhammad Sajid Sharif, Shahzad Büyükgüngör, Orhan |
author_sort | Khan, Islam Ullah |
collection | PubMed |
description | In the title compound, [Ni(C(7)H(4)NS(2))(2)(C(7)H(9)N(3)O(3)S)], the Ni(II) ion is in a slightly distorted N(4)S(2) octahedral coordination environment. The two benzothiazole-2-thiolate ligands chelate via their thiazole N and thiolate S atoms while the methyl 2-(2-aminothiazol-4-yl)-2-(methoxyimino)acetate also acts as a chelate ligand binding through the thiazole and imino N atoms. Intramolecular N—H⋯N, C—H⋯N and C—H⋯O interactions contribute to the molecular conformation. In the crystal structure, intermolecular N—H⋯O hydrogen bonds produce R (1) (2)(6) rings and generate chains along the c axis. An extensive one-dimensional supramolecular network of N—H⋯O hydrogen bonds and C—H⋯π interactions is responsible for the crystal structure stabilization. |
format | Text |
id | pubmed-2979032 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29790322010-12-30 Bis(1,3-benzothiazole-2-thiolato)[(Z)-methyl 2-(2-amino-1,3-thiazol-4-yl)-2-(methoxyimino)acetate]nickel(II) Khan, Islam Ullah Şahin, Onur Jillani, Shehzada Muhammad Sajid Sharif, Shahzad Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(7)H(4)NS(2))(2)(C(7)H(9)N(3)O(3)S)], the Ni(II) ion is in a slightly distorted N(4)S(2) octahedral coordination environment. The two benzothiazole-2-thiolate ligands chelate via their thiazole N and thiolate S atoms while the methyl 2-(2-aminothiazol-4-yl)-2-(methoxyimino)acetate also acts as a chelate ligand binding through the thiazole and imino N atoms. Intramolecular N—H⋯N, C—H⋯N and C—H⋯O interactions contribute to the molecular conformation. In the crystal structure, intermolecular N—H⋯O hydrogen bonds produce R (1) (2)(6) rings and generate chains along the c axis. An extensive one-dimensional supramolecular network of N—H⋯O hydrogen bonds and C—H⋯π interactions is responsible for the crystal structure stabilization. International Union of Crystallography 2010-04-30 /pmc/articles/PMC2979032/ /pubmed/21579063 http://dx.doi.org/10.1107/S1600536810015072 Text en © Khan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Khan, Islam Ullah Şahin, Onur Jillani, Shehzada Muhammad Sajid Sharif, Shahzad Büyükgüngör, Orhan Bis(1,3-benzothiazole-2-thiolato)[(Z)-methyl 2-(2-amino-1,3-thiazol-4-yl)-2-(methoxyimino)acetate]nickel(II) |
title | Bis(1,3-benzothiazole-2-thiolato)[(Z)-methyl 2-(2-amino-1,3-thiazol-4-yl)-2-(methoxyimino)acetate]nickel(II) |
title_full | Bis(1,3-benzothiazole-2-thiolato)[(Z)-methyl 2-(2-amino-1,3-thiazol-4-yl)-2-(methoxyimino)acetate]nickel(II) |
title_fullStr | Bis(1,3-benzothiazole-2-thiolato)[(Z)-methyl 2-(2-amino-1,3-thiazol-4-yl)-2-(methoxyimino)acetate]nickel(II) |
title_full_unstemmed | Bis(1,3-benzothiazole-2-thiolato)[(Z)-methyl 2-(2-amino-1,3-thiazol-4-yl)-2-(methoxyimino)acetate]nickel(II) |
title_short | Bis(1,3-benzothiazole-2-thiolato)[(Z)-methyl 2-(2-amino-1,3-thiazol-4-yl)-2-(methoxyimino)acetate]nickel(II) |
title_sort | bis(1,3-benzothiazole-2-thiolato)[(z)-methyl 2-(2-amino-1,3-thiazol-4-yl)-2-(methoxyimino)acetate]nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979032/ https://www.ncbi.nlm.nih.gov/pubmed/21579063 http://dx.doi.org/10.1107/S1600536810015072 |
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