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5,10,15,20-Tetra-2-furylporphyrin
Molecules of the title macrocycle, C(36)H(22)N(4)O(4), are located on an inversion center. The porphyrin ring shows a wave-like conformation with adjacent pyrrole rings tilted above the porphyrin plane and the interporphyrin distance is 3.584 (3) Å. The dihedral angles between the meso-furyl group...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979040/ https://www.ncbi.nlm.nih.gov/pubmed/21579204 http://dx.doi.org/10.1107/S1600536810014285 |
Sumario: | Molecules of the title macrocycle, C(36)H(22)N(4)O(4), are located on an inversion center. The porphyrin ring shows a wave-like conformation with adjacent pyrrole rings tilted above the porphyrin plane and the interporphyrin distance is 3.584 (3) Å. The dihedral angles between the meso-furyl groups and the porphyrin plane are 38.87 (7) and 48.29 (7)°; these are much smaller than those observed for meso-tetraphenylporphyrin, indicating that the meso-furyl groups are more inclined towards the porphyrin plane. The decrease in the dihedral angle is due to the presence of intramolecular hydroden bonding between the meso-fury O atom and the β-pyrrole CH group. Intramolecular N—H⋯N hydrogen bonds are also present. |
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